Aryl diazonium salts are ubiquitous building blocks in chemistry, as they are useful radical precursors in organic synthesis as well as for the functionalization of solid materials. They can be reduced electrochemically or through a photo-induced electron transfer reaction. Here we provide a detailed picture of the ground and excited-state reactivity of a series of 9 rare and earth abundant photosensitizers with 13 aryl diazonium salts, which also included 3 macrocyclic calix[4]arene tetradiazonium salts. Nanosecond transient absorption spectroscopy confirmed the occurrence of excited-state electron transfer and was used to quantify cage-escape yields, . the efficiency with which the formed radicals separate and escape the solvent cage. Cage-escape yields were large; increased when the driving force for photo-induced electron transfer increased and also tracked with the C-N bond cleavage propensity, amongst others. A photo-induced borylation reaction was then investigated with all the photosensitizers and proceeded with yields between 9 and 74%.
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| http://dx.doi.org/10.1016/j.checat.2022.100490 | DOI Listing |
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