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Porous zeolitic imidazolate frameworks assembled with highly-flattened tetrahedral copper(II) centres and 2-nitroimidazolates. | LitMetric
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Porous zeolitic imidazolate frameworks assembled with highly-flattened tetrahedral copper(II) centres and 2-nitroimidazolates.

Cheolwon Jung Sang Beom Choi Jaewoo Park Minji Jung Jonghoon Kim Hyunchul Oh Jaheon Kim

Chem Commun (Camb)

Department of Chemistry, Soongsil University, Seoul, 06978, Republic of Korea.

Published: March 2023

Cu(II)-based zeolitic imidazolates (Cu-ZIFs), Cu-ZIF-gis and -rho, formulated as Cu(nIm) (nIm = 2-nitroimidazolate) have highly-flattened tetrahedral coordination geometry. Cu-ZIF-gis has 2.4 Å cylindrical pores that can adsorb H gas, and Cu-ZIF-rho has 19.8 Å cages with a BET surface area of 1320 m g.

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http://dx.doi.org/10.1039/d2cc06797hDOI Listing

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