The ancient stable continents are up to 250 km deep, with roots extending into the diamond stability field. These cratons owe their mechanical strength to being cool and rigid, features inherited from extensive melt extraction. The most prominent model for craton formation anticipates dominant melting at relatively shallow depth (50-100 km) above diamond stability, followed by later imbrication to form the deeper roots. Here we present results from thermodynamic and geochemical modelling of melting at sufficiently high temperatures to produce the very magnesian olivine of cratonic roots. The new closed-system and open-system modelling reproduces the observed cratonic mantle mineral compositions by deep (about 200 km) and very hot melting (≥1,800 °C), obviating the need for shallow melting and stacking. The modelled highly magnesian liquids (komatiites) evolve to Al-enriched and Ti-depleted forms, as observed in the greenstone belts at the fossil surface of cratons. The paucity of Ti-depleted komatiite implies that advanced closed-system isochemical melting (>1,825 °C) was much less common than open-system interaction between deeper liquids and melting of existing refractory mantle. The highly refractory compositions of diamond inclusion minerals could imply preferential diamond growth in the more reducing parts of the cratonic root, depleted by ultra-hot melting in response to heat plumes from a deeper former boundary layer that vanished at the end of the Archaean.
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http://dx.doi.org/10.1038/s41586-022-05665-2 | DOI Listing |
Adv Sci (Weinh)
December 2024
Institute of Materials Science, Technische Universität Darmstadt, Peter-Grünberg-Str. 2, D-64287, Darmstadt, Germany.
The design of cathode/electrolyte interfaces in high-energy density Li-ion batteries is critical to protect the surface against undesirable oxygen release from the cathodes when batteries are charged to high voltage. However, the involvement of the engineered interface in the cationic and anionic redox reactions associated with (de-)lithiation is often ignored, mostly due to the difficulty to separate these processes from chemical/catalytic reactions at the cathode/electrolyte interface. Here, a new electron energy band diagrams concept is developed that includes the examination of the electrochemical- and ionization- potentials evolution upon batteries cycling.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Department of Materials Science and Engineering, and State Key Laboratory of Marine Pollution, and Center of Super-Diamond and Advanced Films, City University of Hong Kong, Hong Kong S.A.R. 999077, China.
Metallic 1T phase molybdenum disulfide (MoS) is among the most promising electrode materials for supercapacitors, but its capacitance and cyclability remain to be improved to meet the constantly increasing energy storage needs in portable electronics. In this study, we present a strategy, covalent functionalization, which achieves the improvement of capacitance of metallic 1T phase MoS. Covalently functionalized by the modifier 4-bromobenzenediazonium tetrafluoroborate, the metallic MoS membrane exhibits increased interlayer spacing, slightly curled layered architecture, enhanced charge transfer, and improved adsorption capabilities toward electrolyte molecules and ions.
View Article and Find Full Text PDFArch Biochem Biophys
December 2024
The Division of Structural Biology, The Nuffield Department of Medicine, University of Oxford, UK; The Rosalind Franklin Institute, Harwell Campus, Didcot, OX11 0QS, UK. Electronic address:
Multifunctionality, processivity, and thermostability are critical for the cost-effective enzymatic saccharification of non-food plant biomass polymers such as β-glucans, celluloses, and xylans to generate biofuels and other valuable products. We present molecular insights into a processive multifunctional endo-1,3-1,4-β-d-glucanase (Tt_End5A) from the hyperthermophilic bacterium Thermogutta terrifontis. Tt_End5A demonstrated activities against a broad spectrum of β-polysaccharides, including barley glucan, lichenan, carboxymethyl cellulose, regenerated amorphous cellulose (RAC), Avicel, xylan, laminarin, mannan, curdlan, xanthan, and various chromogenic substrates at pH 7 and temperatures ranging from 70 to 80°C.
View Article and Find Full Text PDFInorg Chem
December 2024
Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-Ku, Sendai 980-8578, Japan.
One of the goals in synthetic chemistry is to obtain compounds featuring unusual valence states that are stable under ambient conditions. At present, stabilizing unusual Pt(III) states is considered difficult, except through direct Pt-Pt bonding such as that in platinum-blues or organometallization using bulky ligands. Pt(III) stabilization is also very difficult in halogen-bridged metal complex chains (MX-Chains).
View Article and Find Full Text PDFBraz Dent J
December 2024
Post-graduate Program in Oral Science, Prosthodontic Unit, Faculty of Odontology, Federal University of Santa Maria(UFSM), Santa Maria, Rio Grande do Sul, Brazil.
This study evaluated the effect of grinding and finishing treatments (polishing or glaze) on the color stability, translucency and opalescence of a translucent zirconia (3Y-TZP) after immersion in red wine. Discs (Ø= 12 mm; thickness 0.8 mm) of 3Y-TZP (Zenostar T, Ivoclar AG) were randomly allocated (n= 8) according to the surface treatment factor: Ctrl - as-sintered; Gr - grinding with diamond bur #4219; Gr + Pol - grinding followed by polishing; Gr + Gl - grinding followed by glaze.
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