Inclusion structures incorporating more than one guest molecule are elusive because confinement alters their molecular properties. We report the solid-state characterization of an inclusion complex comprising two γ-cyclodextrins and two [Cu(2-pyridinemethanolate)(2-pyridinemethanol)]PF units. Quantum calculation reveals that occurs. The confined Cu fragment and the unincluded "linear chain [Cu(2-pyridinemethanolate)(2-pyridinemethanol)]PF" exhibit different properties.
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| http://dx.doi.org/10.1039/d3dt00176h | DOI Listing |
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