Bis[1,2-bis-(4--butyl-phen-yl)ethyl-ene-1,2-di-thiol-ato(1-)]nickel(II) pentane 0.25-solvate.

Acta Crystallogr E Crystallogr Commun

Department of Chemistry, Tulane University, 6400 Freret Street, New Orleans, Louisiana 70118-5698, USA.

Published: February 2023

The title compound, [Ni(CHS)], , is a square-planar -symmetric compound that occurs on a general position in non-centrosymmetric tetra-gonal 422 (No. 92) with ¼ eq of -pentane (CH) as co-crystallite. Intra-ligand bond lengths show the di-thiol-ene ligands to be in their half-oxidized radical monoanionic form. Inter-molecular Bu-C-H⋯arene and Bu-C-H⋯NiSC close contacts guide the packing arrangement for .

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993911PMC
http://dx.doi.org/10.1107/S205698902300097XDOI Listing

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Bis[1,2-bis-(4--butyl-phen-yl)ethyl-ene-1,2-di-thiol-ato(1-)]nickel(II) pentane 0.25-solvate.

Acta Crystallogr E Crystallogr Commun

February 2023

Department of Chemistry, Tulane University, 6400 Freret Street, New Orleans, Louisiana 70118-5698, USA.

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