The biological methanation of H and CO in trickle bed reactors is one promising energy conversion technology for energy storage, but experiences at pilot-scale under real application conditions are still rare. Therefore, a trickle bed reactor with a reaction volume of 0.8 m was constructed and installed in a wastewater treatment plant to upgrade raw biogas from the local digester. The biogas HS concentration of about200 ppm was reduced by half, but an artificial sulfur source was required to completely satisfy the sulfur demand of the methanogens. Increasing the ammonium concentration to > 400 mg/L was the most successful pH control strategy, enabling stable long-term biogas upgrading at a CH production of 6.1 m/(m·d) with synthetic natural gas quality (CH > 98%). The results of this study with a reactor operation period of nearly 450 days, including two shutdowns, represents an important step towards the necessary full-scale integration.
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http://dx.doi.org/10.1016/j.biortech.2023.128868 | DOI Listing |
RSC Adv
January 2025
Department of Chemistry, Chung-Ang University 84 Heukseok-ro, Dongjak-gu Seoul Republic of Korea
The C chemical species, potassium formate (K(HCO)), known as a two-electron reducing agent, finds application in the synthesis of multi-carbon compounds, including oxalate, and plays a crucial role not only in the food and pharmaceutical industries but also across various sectors. However, the direct hydrogenation of CO to produce K(HCO) remains a challenge. Addressing this issue, efficient production of K(HCO) is achieved by integrating CO hydrogenation in a trickle-bed reactor using a heterogeneous catalyst with a novel separation method that utilizes potassium ions from biomass ash for formic acid derivative product isolation.
View Article and Find Full Text PDFMolecules
November 2024
Department of Chemical and Biochemical Engineering, Technical University of Denmark, 2800 Kongens Lyngby, Denmark.
The use of mixed cultures in gas fermentations could reduce operating costs in the production of liquid chemicals such as alcohols or carboxylic acids. However, directing reducing equivalents towards the desired products presents the challenge of co-existing competing pathways. In this study, two trickle bed reactors were operated at acetogenic and chain elongating conditions to explore the fate of electron equivalents (ethanol, H, and CO) and test pH oscillations as a strategy to target chain-elongated products.
View Article and Find Full Text PDFChempluschem
December 2024
Ircelyon, UMR 5256, CNRS, Universite Claude Bernard Lyon 12, Avenue Albert Einstein, F-69626, Villeurbanne Cedex, Lyon, France.
For the first time, the catalytic oxidation of Kraft lignin over a solid heterogeneous catalyst was studied in a continuous lab-scale trickle-bed reactor. This catalytic process is able to depolymerize Kraft lignin and produce phenolic compounds of interest such as vanillin. The impact of operating conditions such as temperature, residence time, contact time, catalyst loading and lignin concentration was evaluated.
View Article and Find Full Text PDFFEMS Microbes
August 2024
Department of Biotechnology, Institute of Microbiology and Microbial Biotechnology, BOKU University, Muthgasse 18, 1190 Vienna, Austria.
J Hazard Mater
December 2024
CAS Key Laboratory of Environmental and Applied Microbiology, Environmental Microbiology Key Laboratory of Sichuan Province, Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041, PR China. Electronic address:
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