Amine-Functionalized Natural Rubber/Mesostructured Silica Nanocomposites for Adsorptive Removal of Clofibric Acid in Aqueous Phase.

This study is the first report on the synthesis, characterization and application of amine-functionalized mesoporous nanocomposites based on natural rubber (NR) and wormhole-like mesostructured silica (WMS). In comparison with amine-functionalized WMS (WMS-NH), a series of NR/WMS-NH composites were synthesized via an in situ sol-gel method in which the organo-amine group was grafted onto the nanocomposite surface via co-condensation with 3-aminopropyltrimethoxysilane (APS) as the amine-functional group precursor. The NR/WMS-NH materials had a high specific surface area (115-492 m g) and total pore volume (0.14-1.34 cm g) with uniform wormhole-like mesoporous frameworks. The amine concentration of NR/WMS-NH (0.43-1.84 mmol g) was increased with an increase in the APS concentration, corresponding to high levels of functionalization with the amine groups of 53-84%. The HO adsorption-desorption measurement revealed that NR/WMS-NH possessed higher hydrophobicity than WMS-NH. The removal of clofibric acid (CFA), a xenobiotic metabolite of the lipid-lowering drug clofibrate, from the aqueous solution using WMS-NH and NR/WMS-NH materials was investigated using a batch adsorption experiment. The adsorption was a chemical process in which the pseudo-second order kinetic model expressed the sorption kinetic data better than the pseudo first-order and Ritchie-second kinetic order model. In addition, the CFA adsorption sorption equilibrium data of the NR/WMS-NH materials were fitted to the Langmuir isotherm model. The NR/WMS-NH with 5% amine loading had the highest CFA adsorption capacity (6.29 mg g).