Carbonate rocks present a complicated pore system owing to the existence of intra-particle and interparticle porosities. Therefore, characterization of carbonate rocks using petrophysical data is a challenging task. Conventional neutron, sonic, and neutron-density porosities are proven to be less accurate as compared to the NMR porosity. This study aims to predict the NMR porosity by implementing three different machine learning (ML) algorithms using conventional well logs including neutron-porosity, sonic, resistivity, gamma ray, and photoelectric factor. Data, comprising 3500 data points, was acquired from a vast carbonate petroleum reservoir in the Middle East. The input parameters were selected based on their relative importance with respect to output parameter. Three ML techniques such as adaptive neuro-fuzzy inference system (ANFIS), artificial neural network (ANN), and functional network (FN) were implemented for the development of prediction models. The model's accuracy was evaluated by correlation coefficient (R), root mean square error (RMSE), and average absolute percentage error (AAPE). The results demonstrated that all three prediction models are reliable and consistent exhibiting low errors and high 'R' values for both training and testing prediction when related to actual dataset. However, the performance of ANN model was better as compared to other two studied ML techniques based on minimum AAPE and RMSE errors (5.12 and 0.39) and highest R (0.95) for testing and validation outcome. The AAPE and RMSE for the testing and validation results were found to be 5.38 and 0.41 for ANFIS and 6.06 and 0.48 for FN model, respectively. The ANFIS and FN models exhibited 'R' 0.937 and 0.942, for testing and validation dataset, respectively. Based on testing and validation results, ANFIS and FN models have been ranked second and third after ANN. Further, optimized ANN and FN models were used to extract explicit correlations to compute the NMR porosity. Hence, this study reveals the successful applications of ML techniques for the accurate prediction of NMR porosity.
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http://dx.doi.org/10.1038/s41598-023-30708-7 | DOI Listing |
Adv Mater
January 2025
Max Planck Institute for Solid State Research, Heisenbergstr. 1, 70569, Stuttgart, Germany.
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Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction, Ministry of Education, State Key Laboratory of Green Pesticide, College of Chemistry, Central China Normal University, Wuhan, China.
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January 2025
Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, United States.
A Pt(II) aqua complex supported by mesoporous silica nanoparticle (MSN)-immobilized sulfonated CNN pincer ligand featuring a rigid SiO tether was prepared. This hybrid material was tested as a catalyst in H/D exchange reactions of C(sp)-H bonds of selected aromatic substrates and DO-2,2,2-trifluoroethanol- (TFE-) mixtures or CDCOD acting as a source of exchangeable deuterium. The catalyst immobilization served as a means to not only enable the catalyst's recyclability but also minimize the coordination of sulfonate groups and the metal centers originating from different catalyst's moieties that would preserve reactive Pt(OH) fragments needed for catalytic C-H bond activation.
View Article and Find Full Text PDFSci Rep
January 2025
School of Safety and Management Engineering, Hunan Institute of Technology, Hengyang, 421002, China.
The extraction of coal seams with high gas content and low permeability presents significant challenges, particularly due to the extended period required for gas extraction to meet safety standards and the inherently low extraction efficiency. Hydraulic fracturing technology, widely employed in the permeability enhancement of soft and low-permeability coal seams, serves as a key intervention. This study focuses on the high-rank raw coal from the No.
View Article and Find Full Text PDFFront Chem
December 2024
Department of Chemistry, University of Wyoming, Laramie, WY, United States.
Covalent integration of polymers and porous organic frameworks (POFs), including metal-organic frameworks (MOFs), covalent organic frameworks (COFs) and hydrogen-bonded organic frameworks (HOFs), represent a promising strategy for overcoming the existing limitations of traditional porous materials. This integration allows for the combination of the advantages of polymers, i.e.
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