The increasing demand for cement due to urbanization growth in Africa countries may result in an upsurge of pollutants associated with its production. One major air pollutant in cement production is nitrogen oxides (NOx) and reported to cause serious damage to human health and the ecosystem. The operation of a cement rotary kiln NOx emission was studied with plant data using the ASPEN Plus software. It is essential to understand the effects of calciner temperature, tertiary air pressure, fuel gas, raw feed material, and fan damper on NOx emissions from a precalcining kiln. In addition, the performance capability of adaptive neuro-fuzzy inference systems and genetic algorithms (ANFIS-GA) to predict and optimize NOx emissions from a precalcining cement kiln is evaluated. The simulation results were in good agreement with the experimental results, with root mean square error of 2.05, variance account (VAF) of 96.0%, average absolute deviation (AAE) of 0.4097, and correlation coefficient of 0.963. Further, the optimal NOx emission was 273.0 mg/m, with the parameters as determined by the algorithm were calciner temperature at 845 °C, tertiary air pressure - 4.50 mbar, fuel gas of 8550 m/h, raw feed material 200 t/h, and damper opening of 60%. Consequently, it is recommended that ANFIS should be combined with GA for effective prediction, and optimization of NOx emission in cement plants.
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http://dx.doi.org/10.1007/s11356-023-26282-0 | DOI Listing |
Sci Total Environ
January 2025
Yunnan Key Laboratory of Internal Combustion Engine, Kunming University of Science and Technology, Kunming 650500, China.
Ammonia is a highly promising carbon-neutral fuel. The use of ammonia as a fuel for internal combustion engines can reduce fossil energy consumption and greenhouse gas emissions. However, the high ignition energy required for ammonia and the slow flame propagation rate result in low combustion efficiency when ammonia is used directly in internal combustion engines.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
January 2025
The Cyprus Institute, Climate and Atmosphere Research Center, 2121, Nicosia, Cyprus.
The production of nitrogen oxides (NO = NO + NO ) is substantial in urban areas and from fossil fuel-fired power plants, causing both local and regional pollution, with severe consequences for human health. To estimate their emissions and implement air quality policies, authorities often rely on reported emission inventories. The island of Cyprus is de facto divided into two different political entities, and as a result, such emissions inventories are not systematically available for the whole island.
View Article and Find Full Text PDFNat Commun
January 2025
Department of Chemical Engineering, University College London, London, WC1E 7JE, UK.
Selective catalytic oxidation (SCO) of NH to N is one of the most effective methods used to eliminate NH emissions. However, achieving high conversion over a wide operating temperature range while avoiding over-oxidation to NO remains a significant challenge. Here, we report a bi-metallic surficial catalyst (PtCuO/AlO) with improved Pt atom efficiency that overcomes the limitations of current catalysts.
View Article and Find Full Text PDFSci Rep
December 2024
Faculty of Education, Shinawatra University, Bangkok, Thailand.
This study aims to reduce engine emissions while maintaining engine performance and providing a sustainable fuel source for long-term use. It introduces a novel approach by combining pine oil (PO) and lemon grass oil (LGO) with diesel fuel in a specific ratio (10% PO + 10% LGO + 80% Diesel). This work is innovative in that it employs these two distinct low-viscosity biofuel blends in conjunction with diesel fuel in an agricultural engine, resulting in reduced carbon footprints in the tailpipe.
View Article and Find Full Text PDFJ Chromatogr A
December 2024
School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China. Electronic address:
The evolution of precursors to form secondary organic aerosol (SOA) is still a challenge in atmospheric chemistry. Chamber experiments were conducted to simulate the ambient OH oxidation of naphthalene and α-pinene, which are typical markers of anthropogenic and biogenic emissions. Particulate matters were sampled by quartz filters and were analyzed by comprehensive two-dimensional gas chromatography (GC×GC) coupled with a thermal desorption system (TD) and a mass spectrometer (MS).
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