Confined directional drying of a colloidal dispersion: kinetic modeling.

We derive a model to describe the dynamics of confined directional drying of a colloidal dispersion. In such experiments, a dispersion of rigid colloids is confined in a capillary tube or a Hele-Shaw cell. Solvent evaporation from the open end accumulates the particles at the tip up to the formation of a porous packing that invades the cell at a rate . Our model based on a classical description of fluid mechanics and capillary phenomena, predicts different regimes for the growth of the consolidated packing, . At early times, the evaporation rate is constant and the growth is linear, ∝ . At longer times, the evaporation rate decreases and the consolidated packing grows as . This slowdown is either related to the recession of the drying interface within the packing thus adding a resistance to evaporation (capillary-limited regime), or to the Kelvin effect which decreases the partial pressure of water at the drying interface (flow-limited regime). We illustrate these results with numerical relations describing hard spheres, showing that these regimes are experimentally observable. Beyond this description of the confined directional drying of colloidal dispersions, our results also highlight the importance of relative humidity control in such experiments.