Topological Defect Guided Order Evolution across the Nematic-Smectic Phase Transition.

Topological defects usually emerge and vary during the phase transition of ordered systems. Their roles in thermodynamic order evolution keep being the frontier of modern condensed matter physics. Here, we study the generations of topological defects and their guidance on the order evolution during the phase transition of liquid crystals (LCs). With a given preset photopatterned alignment, two different types of topological defects are achieved depending on the thermodynamic process. Because of the memory effect of LC director field across the Nematic-Smectic (N-S) phase transition, a stable array of toric focal conic domains (TFCDs) and a frustrated one are generated in S phase, respectively. The frustrated one transfers to a metastable TFCD array with a smaller lattice constant, and further changes to a crossed-walls type N state due to the inheritance of orientational order. A free energy on temperature diagram and corresponding textures vividly describe the phase transition process and the roles of topological defects in the order evolution across the N-S phase transition. This Letter reveals the behaviors and mechanisms of topological defects on order evolution during phase transitions. It paves a way for investigating topological defect guided order evolution which is ubiquitous in soft matter and other ordered systems.