We propose a high-performance vector torsion sensor based on an in-fiber Mach-Zehnder interferometer (MZI), which consists of a straight waveguide inscribed in the core-cladding boundary of the SMF by a femtosecond laser in only one step. The length of the in-fiber MZI is 5 mm, and the whole fabrication time does not exceed 1 min. The asymmetric structure makes the device have high polarization dependence, and the transmission spectrum shows a strong polarization-dependent dip. Since the polarization state of the input light entering the in-fiber MZI varies with the twist of the fiber, torsion sensing can be achieved by monitoring the polarization-dependent dip. Torsion can be demodulated by both the wavelength and intensity of the dip, and vector torsion sensing can be achieved by setting the appropriate polarization state of the incident light. The torsion sensitivity based on intensity modulation can reach 5763.96 dB/(rad/mm). The response of dip intensity to strain and temperature is weak. Furthermore, the in-fiber MZI retains the fiber coating, so it maintains the robustness of the complete fiber structure.
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http://dx.doi.org/10.1364/OE.483885 | DOI Listing |
J Org Chem
December 2024
Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States.
Understanding how changes in structure translate to changes in molecular shape is key to catalyst optimization and molecular design in medicinal chemistry and materials. One key contributor to the molecular shape is the relative orientation of substituents on a scaffold. Macrocyclic metacyclophanes display their two arenes in a parallel or antiparallel fashion, resulting in or conformations that lead to disparate relative orientations of the aryl substituents.
View Article and Find Full Text PDFJ Chem Phys
November 2024
Departament de Fisica, Universitat Politecnica de Catalunya, Campus Nord-Edifici B4-B5, Jordi Girona 1-3, Barcelona E-08034, Spain.
Molecular dynamics simulations at constant temperature and pressure were carried out to investigate the structural, dynamical, and dielectric properties of succinonitrile in its plastic and liquid phases at several thermodynamic states. A six-site united atom model was employed with a force field incorporating an intramolecular torsional term that accurately describes gauche and trans conformers. Analysis of the radial distribution function showed that succinonitrile adopts a body-centered cubic arrangement below its melting point, transitioning to a less ordered state in the liquid phase.
View Article and Find Full Text PDFJ Chem Inf Model
October 2024
Department of Chemistry and Applied Biosciences, ETH Zurich Vladimir-Prelog-Weg 2, Zurich 8093, Switzerland.
Molecular flexibility is a commonly used, but not easily quantified term. It is at the core of understanding composition and size of a conformational ensemble and contributes to many molecular properties. For many computational workflows, it is necessary to reduce a conformational ensemble to meaningful representatives, however defining them and guaranteeing the ensemble's completeness is difficult.
View Article and Find Full Text PDFGeom Dedic
September 2024
Department of Pure Mathematics, University of Waterloo, Waterloo, Canada.
We consider the existence of cohomogeneity one solitons for the isometric flow of -structures on the following classes of torsion-free -manifolds: the Euclidean with its standard -structure, metric cylinders over Calabi-Yau 3-folds, metric cones over nearly Kähler 6-manifolds, and the Bryant-Salamon -manifolds. In all cases we establish existence of global solutions to the isometric soliton equations, and determine the asymptotic behaviour of the torsion. In particular, existence of shrinking isometric solitons on is proved, giving support to the likely existence of type I singularities for the isometric flow.
View Article and Find Full Text PDFPhys Rev Lett
July 2024
Centro de Estudios Científicos (CECs), Av. Arturo Prat 514, Valdivia, Chile and Universidad San Sebastián, General Lagos 1163, Valdivia 5110693, Chile.
In this Letter, we construct a supersymmetric model, obtained by deforming N=2 anti-de Sitter D=3 supergravity through a chiral vector component of the torsion. Moreover, we study the existence of supersymmetric states of such theory by inspecting the presence of Killing spinors on a specific bosonic solution.
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