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Rigid HOCTAPA derivatives as model chelators for the development of Bi(III)-based radiopharmaceuticals. | LitMetric
Octadentate ligands containing ethyl (HOCTAPA), cyclohexyl (HOCTAPA) or cyclopentyl (HOCTAPA) spacers were assessed as chelators for Bi(III)-based radiopharmaceuticals. The HOCTAPA chelator displays excellent properties, including Bi-nuclide radiolabelling under mild conditions, excellent stability in serum and in the presence of competing cations or HDTPA. The poor performance of HOCTAPA appears to be related to the stereochemical activity of the Bi(III) lone pair.
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