Photochemical and electrochemical co-regulation of the BiVO photoanode for water splitting.

Chem Commun (Camb)

School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P. R. China.

Published: March 2023

A novel pretreatment strategy that can regulate the amount of oxygen vacancies (O) across the wormlike-BiVO photoanode by photochemical and electrochemical co-processing. Upon decorating NiFeO as an oxygen evolution cocatalyst for promoting the surface oxidation kinetics, a record-high photocurrent density of 6.42 mA cm is obtained at 1.23 . RHE (100 mW cm).

Download full-text PDF

Source
http://dx.doi.org/10.1039/d2cc07093fDOI Listing

Publication Analysis

Top Keywords

photochemical electrochemical
8
electrochemical co-regulation
4
co-regulation bivo
4
bivo photoanode
4
photoanode water
4
water splitting
4
splitting novel
4
novel pretreatment
4
pretreatment strategy
4
strategy regulate
4

Similar Publications

Print-Light-Synthesis of ruthenium oxide thin film electrodes for electrochemical sensing applications.

Bioelectrochemistry

January 2025

University of Bologna, Department of Industrial Chemistry "Toso Montanari", Center of Chemical Catalysis-C(3), Via Piero Gobetti 85, 40129 Bologna, Italy. Electronic address:

Print-Light-Synthesis (PLS) combines the inkjet printing of a ruthenium precursor ink with the simultaneous photo-induced generation of ruthenium oxide films. During PLS, inkjet-printing generates on conductive as well as insulating substrates micrometer-thin reaction volumes that contain with high precision defined precursor loadings. Upon direct UV light irradiation, the Ru precursor converts to RuO while all other ink components escape in the gas phase.

View Article and Find Full Text PDF

Graphitic carbon nitride (g-C3N4) has gained significant attention as a promising nonmetallic semiconductor photocatalyst due to its photochemical stability, favorable electronic properties, and efficient light absorption. Nevertheless, its practical applications are hindered by limitations such as low specific surface area, rapid recombination of photogenerated charge carriers, poor electrical conductivity, and restricted photo-response ranges. This review explores recent advancements in the synthesis, modification and application of g-C3N4 and its nanocomposites with a focus on addressing these challenges.

View Article and Find Full Text PDF

Unlocking HFIP for Fluoroalkylation with Molecular Photoelectrocatalysis.

Angew Chem Int Ed Engl

January 2025

Xiamen University, Chemistry, 422 South Siming Road, 361005, Xiamen, CHINA.

Despite the increasing interest in radical-based fluoroalkylation techniques, the organofluorine compounds bearing the partially fluorinated hexafluoroisopropyl group remain extremely scarce due to the lack of appropriate reagents. Herein we report an unprecedented photoelectrocatalytic method for the C-H hexafluoroisopropylation of indoles and tryptophan peptides, utilizing the readily available hexafluoro-2-propanol (HFIP) as the fluoroalkylation reagent. In this process, HFIP is converted into hexafluoroisopropyl radicals, enabling fluoroalkylation reactions.

View Article and Find Full Text PDF

High-temperature reduction of TiO causes the gradual formation of structural defects, leading to oxygen vacancy planar defects and giving rise to Magnéli phases, which are substoichiometric titanium oxides that follow the formula Ti O, with 4 ≤ ≤ 9. A high concentration of defects provides several possible configurations for Ti and Ti within the crystal, with the variation in charge ordered states changing the electronic structure of the material. The changes in crystal and electronic structures of Magnéli phases introduce unique properties absent in TiO, facilitating their diverse applications.

View Article and Find Full Text PDF

BiS/BiO(OH) nanorods with internal electric field throughout the entire bulk phase as photoelectrochemical sensing platforms for CYFRA21-1 immunoassay.

Anal Chim Acta

February 2025

Key Laboratory of Chemical Sensing & Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, 250022, Jinan, PR China; Department of Chemistry, Sungkyunkwan University, 16419, Suwon, Republic of Korea. Electronic address:

Photoelectrochemical (PEC) immunosensors are highly promising tools for monitoring biochemical molecules. Constructing high-performance heterojunctions is a general method to improve the sensitivity of PEC immunosensors. The internal electric field (IEF) formed at the heterojunction interface plays a crucial role in coordinating the separation of photogenerated carriers.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!