A copper-catalyzed oxidative cyclization of alkenyl -propargyl ynamides is described. This protocol enables the practical synthesis of diverse spirocyclic γ-lactams bearing an exocyclic double bond with generally high / selectivity in moderate to good yields. Importantly, this copper-catalyzed oxidative cyclization demonstrates a distinctive selectivity in comparison with the related gold catalysis.

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http://dx.doi.org/10.1021/acs.orglett.3c00319DOI Listing

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