A series of modular ImPy-carbene-Au(I) complexes are synthesized and fully characterized both in the solid state and in solution. The presence of oligoaryl units (phenyl and thienyl rings) at the C5-position of the ImPy core (in close proximity to the gold center) imprints on the organometallic species fine-tunable and predictable catalytic properties. A marked accelerating effect was recorded in several [Au(I)]-catalyzed electrophilic activations of unsaturated hydrocarbons when a CF-containing aromatic ring was accommodated at the ImPy core.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954282 | PMC |
| http://dx.doi.org/10.1021/acsorginorgau.1c00052 | DOI Listing |
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