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Stepwise assembly of heterometallic, heteroleptic "triblock Janus-type" metal-organic polyhedra. | LitMetric
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Stepwise assembly of heterometallic, heteroleptic "triblock Janus-type" metal-organic polyhedra.

Cornelia von Baeckmann Sara Ruiz-Relaño Inhar Imaz Marcel Handke Judith Juanhuix Felipe Gándara Arnau Carné-Sanchez Daniel Maspoch

Chem Commun (Camb)

Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, Barcelona 08193, Spain.

Published: March 2023

Increasing the chemical complexity of metal-organic cages (MOCs) or polyhedra (MOPs) demands control over the simultaneous organization of diverse organic linkers and metal ions into discrete caged structures. Herein, we show that a pre-assembled complex of the archetypical cuboctahedral MOP can be used as a template to replicate such caged structure, one having a "triblock Janus-type" configuration that is both heterometallic and heteroleptic.

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 Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10019128PMC
http://dx.doi.org/10.1039/d2cc06815jDOI Listing

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