Phosphonate-Functionalized Polycarbonates Synthesis through Ring-Opening Polymerization and Alternative Approaches.

Polymers (Basel)

Aix Marseille Univ, CNRS, Chemistry Department, Institut de Chimie Radicalaire UMR 7273, Saint Jérôme Campus, 13397 Marseille, France.

Published: February 2023

Well-defined phosphonate-functionalized polycarbonate with low dispersity ( = 1.22) was synthesized using organocatalyzed ring-opening polymerization (ROP) of novel phosphonate-based cyclic monomers. Copolymerization was also performed to access different structures of phosphonate-containing polycarbonates (PC). Furthermore, phosphonate-functionalized PC was successfully synthesized using a combination of ROP and post-modification reaction.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9965847PMC
http://dx.doi.org/10.3390/polym15040955DOI Listing

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