Persulfate (PS) activated by thermal or homogeneous metals can generate reactive oxygen species (ROS) and high-valence-state metals for contaminants degradation, showing great potential for applications. However, thermal effect in peroxymonosulfate (PMS) system with high-valence-state metal is still ambiguous. In this study, divalent copper (Cu(II)) catalysis was taken to explore thermal effect on PMS performance. Results showed that the Sulfamethoxazole (SMX) removal efficiency in the Cu(II)/PMS system at 60 min increased by only 5.9% with temperature increase from 30 °C to 60 °C. Moreover, SMX removal efficiency was excellent at neutral or basic pH, best with PMS concentration of 2.4 mM, and slightly affected by Cu(II) concentration. The singlet oxygen (O) was identified as main active species at low temperature while sulfate radicals (SO) was more effective at high temperature with Cu(II) co-activation. Also, trivalent copper (Cu(III)) was an important active species. The higher Cu(III) content, the better SMX removal efficiency, but the stronger intermediates toxicity. In combination with removal efficiency and intermediates toxicity at different temperatures, 30 °C was the optimal reaction temperature. Overall, this study provides new perspective on utilization of waste heat and high-valence-state metal for organic wastewater treatment in PMS systems.
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http://dx.doi.org/10.1016/j.jcis.2023.02.102 | DOI Listing |
Environ Sci Technol
January 2025
Department of Atmospheric Sciences, University of Utah, Salt Lake City, Utah 84112, United States.
Methane (CH) is a greenhouse gas with a global warming potential 81.2 times higher than carbon dioxide (CO). The intentional emission of oxidants into the atmosphere has been proposed as a geoengineering solution to accelerate the oxidation of CH to CO, thereby reducing surface warming.
View Article and Find Full Text PDFPLoS One
January 2025
Department of Computer Science, National Textile University, Faisalabad, Pakistan.
Accurate diagnosis of pancreatic cancer using CT scan images is critical for early detection and treatment, potentially saving numerous lives globally. Manual identification of pancreatic tumors by radiologists is challenging and time-consuming due to the complex nature of CT scan images and variations in tumor shape, size, and location of the pancreatic tumor also make it challenging to detect and classify different types of tumors. Thus, to address this challenge we proposed a four-stage framework of computer-aided diagnosis systems.
View Article and Find Full Text PDFCell Rep
January 2025
Experimental Immunology Branch, National Cancer Institute, National Institutes of Health, Bethesda, MD 20892, USA. Electronic address:
Tumor-draining lymph node dendritic cells (DCs) are poor stimulators of tumor antigen-specific CD4 T cells; however, the mechanism behind this defect is unclear. We now show that, in tumor-draining lymph node DCs, a large proportion of major histocompatibility complex class II (MHC-II) molecules retains the class II-associated invariant chain peptide (CLIP) fragment of the invariant chain bound to the MHC-II peptide binding groove due to reduced expression of the peptide editor H2-M and enhanced activity of the CLIP-generating proteinase cathepsin S. The net effect of this is that MHC-II molecules are unable to efficiently bind antigenic peptides.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Texas A&M University, Chemistry, UNITED STATES OF AMERICA.
The functionalization of pyridines at positions remote to the N-atom remains an outstanding problem in organic synthesis. The inherent challenges associated with overriding the influence of the embedded N-atom within pyridines was overcome using n-butylsodium, which provided an avenue to deprotonate and functionalize the C4-position over traditionally observed addition products that are formed with organolithium bases. In this work, we show that freshly generated 4-sodiopyrdines could undergo transition metal free alkylation reactions directly with a variety of primary alkyl halides bearing diverse functional groups.
View Article and Find Full Text PDFEnviron Geochem Health
January 2025
College of Resource and Environmental Engineering, Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resource, Wuhan University of Science and Technology, Wuhan, 430081, People's Republic of China.
Cadmium (Cd) contamination in aquatic systems is a widespread environmental issue. In this study, a solid waste iron tailings and biochar hybrid (Fe-TWBC) was successfully synthesized derived from co-pyrolysis of peanut shell and tailing waste (Fe-TW). Characterization analyses showed that the metal oxides from solid waste iron tailings successfully loaded onto the biochar surface, with more functional groups in Fe-TWBC.
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