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Bidirectional Anions Gathering Strategy Afford Efficient Mixed PbSn Perovskite Solar Cells. | LitMetric

Bidirectional Anions Gathering Strategy Afford Efficient Mixed PbSn Perovskite Solar Cells.

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Key Laboratory of Photovoltaic and Energy Conservation Materials, Institute of Solid-State Physics, Hefei Institutes of Physical Science, Chinese Academy of Science, Hefei, 230031, China.

Published: May 2023

AI Article Synopsis

Article Abstract

Mixed lead-tin (PbSn) perovskite solar cells (PSCs) possess low toxicity and adjustable bandgap for both single-junction and all-perovskite tandem solar cells. However, the performance of mixed PbSn PSCs still lags behind the theoretical efficiency. The uncontrollable crystallization and the resulting structural defect are important reasons. Here, the bidirectional anions gathering strategy (BAG) is reported by using Methylammonium acetate (MAAc) and Methylammonium thiocyanate (MASCN) as perovskite bulk additives, which Ac escapes from the perovskite film top surface while SCN gathers at the perovskite film bottom in the crystallization process. After the optoelectronic techniques, the bidirectional anions movement caused by the top-down gradient crystallization is demonstrated. The layer-by-layer crystallization can collect anions in the next layer and gather at the broader, enabling a controllable crystallization process, thus getting a high-quality perovskite film with better phase crystallinity and lower defect concentration. As a result, PSCs treated by the BAG strategy exhibit outstanding photovoltaic and electroluminescent performance with a champion efficiency of 22.14%. Additionally, it demonstrates excellent long-term stability, which retains ≈92.8% of its initial efficiency after 4000 h aging test in the N glove box.

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Source
http://dx.doi.org/10.1002/smll.202207480DOI Listing

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