Herein, an electrocatalyst with PdNi nanoclusters, supporting multiwalled carbon nanotubes (MWCNTs) (referred to PdNi/CNTs), was fabricated with deep eutectic solvents (DES), which simultaneously served as reducing agent, dispersant, and solvent. The mass activity of the catalyst for formic acid oxidation reaction (FAOR) was increased nearly four times compared to a Pd/C catalyst. The excellent catalytic activity of PdNi/CNTs was ascribed to the special nanocluster structure and appropriate Ni doping, which changed the electron configuration of Pd to reduce the d-band and to produce a Pd-Ni bond as a new active sites. These newly added Ni sites obtained more OH to release more effective active sites by interacting with the intermediate produced in the first step of FAOR. Hence, this study provides a new method for preparing a Pd-Ni catalyst with high catalytic performance.
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http://dx.doi.org/10.3390/nano13040755 | DOI Listing |
Nanomaterials (Basel)
February 2023
College of Chemistry, Xiangtan University, Xiangtan 411105, China.
Herein, an electrocatalyst with PdNi nanoclusters, supporting multiwalled carbon nanotubes (MWCNTs) (referred to PdNi/CNTs), was fabricated with deep eutectic solvents (DES), which simultaneously served as reducing agent, dispersant, and solvent. The mass activity of the catalyst for formic acid oxidation reaction (FAOR) was increased nearly four times compared to a Pd/C catalyst. The excellent catalytic activity of PdNi/CNTs was ascribed to the special nanocluster structure and appropriate Ni doping, which changed the electron configuration of Pd to reduce the d-band and to produce a Pd-Ni bond as a new active sites.
View Article and Find Full Text PDFPhys Chem Chem Phys
February 2023
Satyendra Nath Bose National Centre for Basic Sciences, JD Block, Sector-III, Salt Lake City, Kolkata 700 106, India.
The three well-known orderings of the two constituting atomic species in a bimetallic nano-alloy - core-shell, Janus and mixed structural patterns - may be interconvertible depending on the synthesis conditions. Using first principles electronic structure calculations in the present work, we look for the microscopic origin for such structural transformation considering eight Pd-related bimetallic nano-alloys. Our analysis shows that it is the change in atom-atom covalency that is responsible for such structural transformation.
View Article and Find Full Text PDFOrg Lett
May 2014
Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research (NIPER), Sector 67, S. A. S. Nagar 160 062, Punjab, India.
The palladium-nickel binary nanocluster is reported as a new catalyst system for Suzuki-Miyaura cross-coupling of ortho-heterocycle-tethered sterically hindered aryl bromides. The inferior results obtained with the reported Pd/Ni salts/complexes or individual Pd/Ni nanoparticles as catalyst reveal the cooperative catalytic effect of the Pd and Ni nanoparticles in the Pd-Ni nanocluster. The broad substrate scope with respect to variation of the 2-arylbenzoxazole moiety and boronic acids, which offers a means for diversity generation and catalyst recyclability, marks a distinct advantage.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!