A synthetically controllable two-step spin transition was observed in iron(II) spin crossover nanoparticles of the dehydrated one-dimensional coordination polymer [Fe(NHtrz)]Br (NHtrz = 4-amino-1,2,4-triazole) using the reverse micellar method. The change from two-step to one-step hysteretic characteristics succeeded by changing the reaction time.
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http://dx.doi.org/10.1039/d2dt04118a | DOI Listing |
Chemistry
January 2025
School of Chemistry, University College Dublin, Belfield, Dublin 4, D04 N2E5, Ireland.
Symmetry breaking spin state transitions in two of three isostructural salts of Mn spin crossover cations, [Mn(3-OMe-5-NO-sal323)], with heavy anions are reported. The ReO (1) salt undergoes two-step spin crossover which is coupled with a re-entrant symmetry breaking structural phase transition between a high temperature phase (S=2, C2/c), an intermediate ordered phase (S=1/S=2, P2/c), and a low temperature phase (S=1, C2/c). The AsF (2) complex undergoes an abrupt transition between a high temperature phase (S=2, C2/c) and a low temperature ordered phase (S=1/S=2, P ).
View Article and Find Full Text PDFNanoscale
January 2025
Department of Materials Science, Institute of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8573, Japan.
Pyrrole in a cholesteric liquid crystal was discharged using a Tesla coil to generate pyrrole radicals, affording linear-shaped nano-ordered pyrrole oligomers. Subsequently, the electrochemical polymerisation of a pre-oriented pyrrole oligomer having good affinity for liquid crystals was performed to achieve polypyrrole-imprinted asymmetry from the cholesteric liquid crystal structure. The resultant polymers were analysed using polarising optical microscopy observations, scanning electron microscopy, electrochemistry, optical spectroscopy, and electron spin resonance.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
December 2024
Department of Mechanical and Energy Engineering, Southern University of Science and Technology, Shenzhen 518055, China.
Ferroelectric nematic liquid crystals are polar fluids characterized by microscopic orientational ordering and macroscopic spontaneous polarizations. Within these fluids, domain walls that separate regions of different polarizations are ubiquitous. We demonstrate that the π walls in films of the polar fluids consist of twin half-integer surface disclinations spaced horizontally, enclosing a subdomain where the polarization exhibits left- or right-handed π twists across the film.
View Article and Find Full Text PDFJ Environ Manage
January 2025
College of Environmental and Chemical Engineering, Dalian University, Dalian, 116622, China. Electronic address:
Bisphenol A (BPA) is considered to be a typical endocrine-disrupting compounds (EDCs), and its widespread existence in nature is quite harmful to human and ecological environment. The S-scheme n-n heterojunction composite (BiOCO/BiOS) was constructed via a facile two-step chemical precipitation method for the removal of BPA in water environment. The optimal composite catalyst exhibited outstanding catalytic activity for BPA, obtaining approximately 0.
View Article and Find Full Text PDFDalton Trans
January 2025
Xi'an Rare Metal Materials Institute Co., Ltd, Xi'an 710016, P. R. China.
Spin-crossover (SCO) at room temperature is a pivotal goal within the field of molecular magnetism. Herein, we attempt to assemble Fe SCO complexes using a substituted Hqsal ligand, HL (-(8-quinolyl)-2,3-dihydroxybenzaldimine). Two complexes [Fe(HL)]·X·2MeCN (X = BF for 1 and X = ClO for 2) were obtained and characterized.
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