Solid-state batteries have become one of the hottest research areas today, due to the use of solid-state electrolytes enabling the high safety and energy density. Because of the interaction with electrolyte salts and the abundant ion transport sites, natural polysaccharide polymers with rich functional groups such as -OH, -OR or -COO etc. have been applied in solid-state electrolytes and have the merits of possibly high ionic conductivity and sustainability. This review summarizes the recent progress of natural polysaccharides and derivatives for polymer electrolytes, which will stimulate further interest in the application of polysaccharides for solid-state batteries.
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