Type II and IV twins with irrational twin boundaries are studied by high-resolution transmission electron microscopy in two plagioclase crystals. The twin boundaries in these and in NiTi are found to relax to form rational facets separated by disconnections. The topological model (TM), amending the classical model, is required for a precise theoretical prediction of the orientation of the Type II/IV twin plane. Theoretical predictions also are presented for types I, III, V, and VI twins. The relaxation process that forms a faceted structure entails a separate prediction from the TM. Hence, faceting provides a difficult test for the TM. Analysis of the faceting by the TM is in excellent agreement with the observations.
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http://dx.doi.org/10.1073/pnas.2215085120 | DOI Listing |
Sci Rep
January 2025
Research Institute of Interdisciplinary Science, School of Materials Science and Engineering, Dongguan University of Technology, Dongguan, 523808, China.
Manufacturing of metallic components using additive manufacturing technique is of great interest for the industrial applications. Here, the mechanical and microstructural responses of a 316 L stainless steel (316LSS) built by selective laser melting (SLM) with XOY and XOZ directions were revealed by performing in situ neutron diffraction tensile tests. The tensile strength of the XOY-printed samples reaches 700 MPa, while the tensile strength of the XOZ-printed samples is less than 600 MPa.
View Article and Find Full Text PDFSmall
January 2025
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, China.
Fivefold twins are extensively present in nanoparticles and nanowires, enhancing their performance in physical, chemical, and mechanical properties. However, a deep insight into the correlation between mechanical properties and fivefold twins in bulk nanograined materials is lacking due to synthesis difficulties. Here, a bulk fivefold-twinned nanograined Ni is synthesized via electrodeposition.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Huazhong University of Science and Technology, School of Materials Science and Engineering, 1037 Luoyu Road, 430074, Wuhan, CHINA.
Organics electrooxidation coupled hydrogen production has attracted increasing attention due to the low operation voltage. Nevertheless, the spontaneous production of hydrogen coupled with organics valorization remains challenging. Herein, we develop ultrathin Au/Pt twin nanowire (NW) catalysts for both electrochemical glucose oxidation and hydrogen evolution reaction towards a spontaneous hydrogen production system.
View Article and Find Full Text PDFACS Nano
January 2025
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China.
Nanotwinned materials have recently attracted intense interest since they often exhibit excellent mechanical properties that are far superior to those of the corresponding single crystals. However, how nanotwinned structures affect the physical properties of functional materials remains almost unexplored. In this study, we demonstrate ferrimagnetism in a nanotwinned antiferromagnetic CrO thin film.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Materials Chemistry, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia.
Nanoparticulate electrocatalysts for the oxygen reduction reaction are structurally diverse materials. Scanning transmission electron microscopy (STEM) has long been the go-to tool to obtain high-quality information about their nanoscale structure. More recently, its four-dimensional modality has emerged as a tool for a comprehensive crystal structure analysis using large data sets of diffraction patterns.
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