AI Article Synopsis

  • This paper presents a fiber-optic sensor array utilizing Fabry-Perot interference and machine learning to identify volatile organic liquids (VOLs).
  • The sensor array includes three types of optical fiber tips—an intrinsic flat endface, a hydrophobic-coated endface, and a hydrophilic-coated endface—to enhance classification accuracy.
  • Machine learning methods, particularly convolutional neural networks, effectively classify different organic liquids by analyzing time-transient response signals from droplet evaporation, demonstrating improved performance through diverse data collection.

Article Abstract

In this paper, we report an array of fiber-optic sensors based on the Fabry-Perot interference principle and machine learning-based analyses for identifying volatile organic liquids (VOLs). Three optical fiber tip sensors with different surfaces were included in the array of sensors to improve the accuracy for identifying liquids: an intrinsic (unmodified) flat cleaved endface, a hydrophobic-coated endface, and a hydrophilic-coated endface. The time-transient responses of evaporating droplets from the optical fiber tip sensors were monitored and collected following the controlled immersion tests of 11 different organic liquids. A continuous wavelet transform was used to convert the time-transient response signal into images. These images were then utilized to train convolution neural networks for classification (identification of VOLs). We show that diversity in the information collected using the array of three sensors helps machine learning-based methods perform significantly better. We explore different pipelines for combining the information from the array of sensors within a machine learning framework and their effect on the robustness of models. The results showed that the machine learning-based methods achieved high accuracy in their classification of different liquids based on their droplet evaporation time-transient events.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9909791PMC
http://dx.doi.org/10.1021/acsomega.2c05451DOI Listing

Publication Analysis

Top Keywords

organic liquids
12
machine learning-based
12
volatile organic
8
combining array
8
array fiber-optic
8
fiber-optic sensors
8
sensors machine
8
machine learning
8
optical fiber
8
fiber sensors
8

Similar Publications

Tailoring molecular diffusion in core-shell zeolite imidazolate framework composites realizes efficient kinetic separation of xylene isomers.

Angew Chem Int Ed Engl

January 2025

Zhejiang University, Key Laboratory of Biomass Chemical Engineering of the Ministry of Education, College of Chemical and Biological Engineering, 866 Yuhangtang Road, Xihu District, hangzhou City, 310058, Hangzhou, CHINA.

The separation of xylene isomers is a critical and energy-intensive process in the petrochemical industry, primarily due to their closely similar molecular structures and boiling points. In this work, we report the synthesis and application of a novel core-shell zeolitic imidazolate framework (ZIF) composite, ZIF-65@ZIF-67, designed to significantly enhance the kinetic separation of xylene isomers through a synergistic "shell-gated diffusion and core-facilitated transport" strategy. The external ZIF-67 shell selectively restricts the diffusion of larger isomers (MX and OX), while the internal ZIF-65 core accelerates the diffusion of PX, thereby amplifying the diffusion differences among the isomers.

View Article and Find Full Text PDF

Compound-specific stable isotope analysis (CSIA) using liquid chromatography-isotope ratio mass spectrometry (LC-IRMS) is a powerful tool for determining the isotopic composition of carbon in analytes from complex mixtures. However, LC-IRMS methods are constrained to fully aqueous eluents. Previous efforts to overcome this limitation were unsuccessful, as the use of organic eluents in LC-IRMS was deemed impossible.

View Article and Find Full Text PDF

Triterpenoids are known for their promising biological activities, and there is a growing focus on green extraction methods for these compounds. In this study, ultrasound-assisted deep eutectic solvents were employed to extract triterpenoids from persimmon leaves, with choline chloride-lactic acid identified as an effective green solvent. The extraction conditions were carefully optimized using response surface methodology, resulting in an extraction efficiency of 12.

View Article and Find Full Text PDF

Mechanochemical Synthesis of Type III Porous Liquids from Solid Precursors for the Removal and Conversion of Waste CO from CH.

Adv Mater

January 2025

State Key Laboratory of Coordination Chemistry, Key Laboratory of Mesoscopic Chemistry of MOE, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, P. R. China.

Porous liquids (PLs) have emerged as a promising class of flow porous materials, offering distinctive benefits for sustainable separation processes coupled with catalytic transformations in the chemical industry. Despite their potential, challenges remain in the realms of synthesis complexity, stability, and the strategic engineering of separation and catalytic sites. In this study, a scalable mechanochemical synthetic approach is reported to fabricate Type III PLs from solid precursors with high stability.

View Article and Find Full Text PDF

The integration of hydrogen-bonded organic frameworks (HOFs) with flexible electronic technologies offers a promising strategy for monitoring detailed health information, owing to their inherent porosity, excellent biocompatibility, and tunable catalytic capabilities. However, their application in wearable and real-time health monitoring remains largely unexplored, primarily due to the mechanical mismatch between the traditionally fragile HOFs particles and the softness of human skin. Herein, this study demonstrates an epidermal biosensor that maintains reliable sensing capability even under extreme deformation and complex environmental conditions by integrating HOFs films with wavy bioelectrodes.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!