The exploration of the propensity of engineered materials to bring forward innovations predicated on their periodic nanostructured tailoring rather than the features of their individual compounds is a continuous pursuit that has propelled optical sensors to the forefront of ultra-sensitive bio-identification. Herein, a numerical analysis based on the Finite Element Method (FEM) was used to investigate and optimize the optical properties of a unidirectional asymmetric dimer photonic crystal (PhC). The proposed device has many advantages from a nanofabrication standpoint compared to conventional PhCs sensors, where integrating defects within the periodic array is imperative. The eigenvalue and transmission analysis performed indicate the presence of a protected, confined mode within the structure, resulting in a Fano-like response in the prohibited states. The optical sensor demonstrated a promising prospect for monitoring the DNA hybridization process, with a quality factor (QF) of roughly 1.53×105 and a detection limit (DL) of 4.4×10-5 RIU. Moreover, this approach is easily scalable in size while keeping the same attributes, which may potentially enable gaze monitoring.
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http://dx.doi.org/10.3390/nano13030375 | DOI Listing |
J Phys Chem Lett
December 2024
Molecular Spectroscopy Laboratory, RIKEN, 2-1 Hirosawa Wako, Saitama 351-0198, Japan.
[Pt(NCN)MeCN] (NCN = 1,3-di(2-pyridyl)benzene, MeCN = acetonitrile) forms oligomers in the ground state due to metallophilic interactions, and a Pt-Pt bond is formed with photoexcitation. Ultrafast excited-state dynamics of the [Pt(NCN)MeCN] dimer in acetonitrile is investigated by femtosecond time-resolved absorption (TA) and picosecond emission spectroscopy. The femtosecond TA signals exhibit 60 cm oscillations arising from the Pt-Pt stretching motion in the S dimer.
View Article and Find Full Text PDFBeilstein J Org Chem
December 2024
Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), CNRS-Université de Strasbourg (UMR 7504), F-67034 Strasbourg, France.
The high potential of non-covalent arene-fluoroarene intermolecular interactions in the design of liquid crystals lies in their ability to strongly promote self-assembly, improve the order and stability of the supramolecular mesophases, and enable tuneability of the optical and electronic properties, which can potentially be exploited for advanced applications in display technologies, photonic devices, sensors, and organic electronics. We recently successfully reported the straightforward synthesis of several mesogens containing four lateral aliphatic chains and derived from the classical triphenylene core self-assembling in columnar mesophases based on this paradigm. These mesogenic compounds were simply obtained in good yields by the nucleophilic substitution (SFAr) of various types of commercially available fluoroarenes with the electrophilic organolithium derivatives 2,2'-dilithio-4,4',5,5'-tetraalkoxy-1,1'-biphenyl (2Li- ).
View Article and Find Full Text PDFPhys Rev Lett
December 2024
Department of Physics and Astronomy, and Smalley-Curl Institute, Rice University, Houston, Texas 77251-1892, USA.
The hybrid quantum system of cold atomic gas and optical cavity can host many exotic phenomena including phase transitions and multistabilities. In this Letter, we investigate the effect of photon hopping between two Dicke cavities and show rich quantum phases for steady states and dynamic processes. Starting from a generic dimer system where the two cavities are not necessarily identical, we analytically obtain all possible steady-state phases and confirm their existence by numerical calculations.
View Article and Find Full Text PDFNucl Med Commun
December 2024
Department of Applied Computing, Michigan Technological University.
Dementia with Lewy bodies (DLB) and Parkinson's disease dementia (PDD) are closely related neurodegenerative conditions within the Lewy body spectrum. The relationship between DLB and PDD remains debated, with ongoing discussion about whether they are distinct diseases or different manifestations of the same disorder. This study aimed to identify differences in cerebral perfusion patterns between DLB and PDD patients.
View Article and Find Full Text PDFNanoscale Horiz
December 2024
Department of Physics, Paderborn University, 33098 Paderborn, Germany.
Realizing plasmonic nanogaps with a refractive index ( = 1) environment in metallic nanoparticle (NP) structures is highly attractive for a wide range of applications. So far in self-assembly-based approaches, without surface functionalization of metallic NPs, achieving such extremely small nanogaps is challenging. Surface functionalization introduces changes in the refractive index at nanogaps, which in turn deteriorates the desired plasmonic properties.
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