Fabrication and catalytic properties of nanorod-shaped (Pt-Pd)/CeO composites.

RSC Adv

Xi'an Key Laboratory of Advanced Photo-electronics Materials and Energy Conversion Device, Key Laboratory of Organic Polymer Photoelectric Materials, School of Electronic Information, Xijing University Xi'an 710123 P. R. China.

Published: January 2023

Nanorod-supported (Pt-Pd)/CeO catalysts were synthesized by a simple method of dealloying AlCe Pt Pd ( = 0, 0.075, 0.1, 0.15, 0.2, 0.3) alloy ribbons. SEM and TEM characterization implied that after calcination treatment, the achieved resultants exhibited interspersed nanorod structures with a rich distribution of nanopores. Catalytic tests showed that the (Pt-Pd)/CeO catalyst calcined at 300 °C exhibited the highest catalyst activity for CO oxidation when compared with other catalysts prepared at different noble metal ratios or calcined at other temperatures, whose complete reaction temperature was as low as 100 °C. The outstanding catalytic performance is ascribed to the stable framework structure, rich gas pathways and collaborative effect between the noble Pt and Pd bimetals.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9847492PMC
http://dx.doi.org/10.1039/d2ra07395aDOI Listing

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