Sustainable materials for remediation of pollutants from water is the need of the hour. In this study two carbonaceous adsorbents prepared through hydrothermal carbonisation and pyrolysis from arecanut husk fiber, an agricultural waste material were used for the adsorption of uranium from water. Batch adsorption data as interpreted using the Langmuir model showed adsorption capacities of 250 mg g and 200 mg g respectively at pH 6 for the hydrochar (AHFC) and the pyrochar (AHFT) exceeding that reported for most of the unmodified biochars. The adsorption followed pseudo-second order kinetics and was exothermic in nature. The high selectivity and excellent removal efficiencies on application to environmental ground water samples and good regeneration capacity make these sorbents promising eco-friendly materials for uranium remediation from water.
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http://dx.doi.org/10.1039/d2ra08333g | DOI Listing |
Toxicol Res (Camb)
February 2025
Toxicology Centre, University of Saskatchewan, 44 Campus Drive, Saskatoon, SK S7N 5B3, Canada.
The mining industry, including uranium mining and milling, is of high importance in Canada. It is, however, important to consider that ore processing can result in the creation of by-products that contain radionuclides such as radium-226 (Ra). Even with the strict discharge regulations in place, there is limited evidence to suggest that the current Canadian regulatory thresholds for Ra are protective for aquatic life.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
January 2025
Departamento de Ciência E Tecnologia de Alimentos, Universidade Federal de Santa Catarina, Rod. Admar Gonzaga, 1346, Itacorubi, Florianópolis, Santa Catarina, 88034-001, Brazil.
Technological advances have led to a proportional increase in the deposition of contaminants across various environmental compartments, including water sources. Heavy metals, also known as potentially toxic metals, are of particular concern due to their significant harmful impacts on environmental and human health. Among the available methods for mitigating the threat of these metals in water, solar radiation-based technologies stand out for their cleanliness, cost-effectiveness, and efficiency in removing or reducing the toxicity of heavy metals.
View Article and Find Full Text PDFRadiat Environ Biophys
December 2024
Radiation Protection Bureau, Health Canada, 775 Brookfield Road, Ottawa, ON, K1A 1C1, Canada.
The Canadian Guidelines for the Management of Naturally Occurring Radioactive Materials (NORM) have been developed to manage radiation doses received in workplaces involving NORM, such as mineral extraction and processing, oil and gas production, metal recycling or water treatment facilities. This management strategy works well for most naturally occurring radioactive materials in workplaces, with the exception of radon. Radon is a naturally occurring radioactive gas generated by the decay of uranium-bearing minerals in rocks and soils.
View Article and Find Full Text PDFNano Lett
January 2025
National Key Laboratory of Uranium Resources Exploration-Mining and Nuclear Remote Sensing, East China University of Technology, Nanchang 330013, China.
Efficient sacrificial-agent-free photosynthesis of HO from air and water represents the greenest, lowest-cost, most real-time avenue for HO production but remains a challenging issue. Here, we show a general and effective approach through a structural design on covalent organic frameworks (COFs) with asymmetric dual-function hybrid linkages for boosting the HO photosynthesis of the COFs. Through such design we can equip a COF with not only a catalytic active center but also a special function for isolating the D-A motif, which consequently endows the COF (CI-COF) built on asymmetric dual-function hybrid linkages with a significantly enhanced efficiency in the generation, transmission, and separation of photogenerated carriers, relative to the COF (II-COF and CC-COF) built on symmetric single-function single linkages.
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