Atomic/molecular layer deposition (ALD/MLD) allows for the direct gas-phase synthesis of crystalline metal-organic framework (MOF) thin films. Here, we show for the first time using krypton and methanol physisorption measurements that ALD/MLD-fabricated copper 1,4-benzenedicarboxylate (Cu-BDC) ultrathin films possess accessible porosity matching that of the corresponding bulk MOF.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9887593 | PMC |
| http://dx.doi.org/10.1021/acsanm.2c04934 | DOI Listing |
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