Enhanced Visible-Light-Induced Photocatalytic Activity in M(III)Salophen-Decorated TiO Nanoparticles for Heterogeneous Degradation of Organic Dyes.

In this work, the construction of two heterojunction photocatalysts by coordinative anchoring of M(salophen)Cl complexes (M = Fe(III) and Mn(III)) to rutile TiO through a silica-aminopyridine linker (SAPy) promotes the visible-light-assisted photodegradation of organic dyes. The degradation efficiency of both cationic rhodamine B (RhB) and anionic methyl orange (MO) dyes by Fe- and Mn-TiO-based catalysts in the presence of HO under sunlight and low-wattage visible bulbs (12-18 W) is investigated. Anionic MO is more degradable than cationic RhB, and the Mn catalyst shows more activity than its Fe counterpart. Action spectra demonstrate the maximum apparent quantum efficiency (AQY) at 400-450 nm, confirming the visible-light-driven photocatalytic reaction. The enhanced photocatalytic activity might be attributed to the improved charge transfer in the heterojunction photocatalysts evidenced by photoluminescence (PL) and electrochemical impedance spectroscopy (EIS) analyses. A radical pathway for the photodegradation of dyes is postulated based on scavenging experiments and spectral data. This work provides new opportunities for constructing highly efficient catalysts for wastewater treatment.