AI Article Synopsis
- The research introduces BNOF-1, the first microporous crystalline framework made using dative B←N bonds, addressing the challenge of lack of permanent porosity in previous frameworks.
- BNOF-1 is created from a cost-effective monomer, 4-pyridine boronic acid, and features a high BET surface area of 1345 m²/g, making it one of the most porous materials in its category.
- It demonstrates efficient separation of CH/CO mixtures and can be regenerated in organic solvents without performance loss, suggesting its potential for various applications in material science.
Article Abstract
The utilization of dative B←N bonds for the creation of crystalline organic framework (BNOF) has increasingly received intensive interest; however, the shortage of permanent porosity is an obstacle that must be overcome to guarantee their application as porous materials. Here, we report the first microporous crystalline framework, BNOF-1, that is assembled through sole monomers, which can be scalably synthesized by the cheap 4-pyridine boronic acid. The 2D networks of BNOF-1 were stacked in parallel to generate a highly porous supramolecular open framework, which possessed not only the highest BET surface area of 1345 m g amongst all of the BNOFs but also features a record-high uptake of CH and CO in covalent organic framework (COF) materials to date. Dynamic breakthrough experiments demonstrated that BNOF-1 material can efficiently separate CH/CO mixtures. In addition, the network can be regenerated in organic solvents with no loss in performance, making its solution processable. We believe that BNOF-1 would greatly diversify the reticular chemistry and open new avenues for the application of BNOFs.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9847669 | PMC |
| http://dx.doi.org/10.1039/d2sc06016g | DOI Listing |
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