Road traffic is the main contributor to NO emissions in many European cities, causing that the current limit values for the protection of human health are exceeded. The use of photocatalytic compounds that incorporate titanium dioxide (TiO) is frequently proposed as abatement technology but its depolluting effectiveness on a real scale is still being investigated. In this work, the potential removal capacity of NO that selected TiO-based materials would have if they were implemented in a street in the municipality of Alcobendas (Community of Madrid, Spain) has been evaluated. The number of avoided NO-related deaths over the locality across the period 2001-2019 have been inferred. Moreover, the saving associated with the estimated removal of ambient NO due to the use of photocatalytic materials and costs generated by their acquisition and implementation in the selected urban environment were briefly studied. Attributable mortality due to NO concentrations for Alcobendas has been estimated in 289 deaths, being 9241 the total deaths due to natural cause. This presents a monthly variation associated with the evolution of both mortality due to natural causes and the average concentrations of NO. The reduction in mortality via the hypothetical implantation of photocatalytic materials throughout the municipality, assuming ideal conditions for their optimal performance, would be a maximum of 3%. In addition, a saving of €5708 yr km related to NO damage costs of transport was obtained. A total cost of k€4750.5 km was associated to the purchase of photocatalytic materials and their application to all surfaces in that area. This technology has a big elimination potential in controlled conditions but a low reduction of ambient NO is provided when implemented in real outdoor urban scenarios. Its use can be recommended incorporated into engineering designs and applications, complementing other abatement measures, to reduce NO mortality in urban areas.
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http://dx.doi.org/10.1016/j.envpol.2023.121203 | DOI Listing |
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January 2025
College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao, 266042, P. R. China.
The photocatalytic reduction of CO in water to produce fuels and chemicals is promising while challenging. However, many photocatalysts for accomplishing such challenging task usually suffer from unspecific catalytic active sites and the inefficient charge carrier's separation. Here, a site-specific single-atom Ni/TiO catalyst is reported by in situ topological transformation of Ni-Ti-EG bimetallic metal-organic frameworks.
View Article and Find Full Text PDFJ Phys Chem C Nanomater Interfaces
January 2025
Surface Science Laboratory, Faculty of Engineering and Natural Sciences, Tampere University, P.O. Box 692, FI-33014 Tampere, Finland.
Nanopowders or films of pure and mixed oxides in nanoparticulate form have gained specific interest due to their applicability in functionalizing high-surface-area substrates. Among various other applications, our presented work primarily focuses on the behavior of TiO as a photocatalyst deposited by atomic layer deposition (ALD) on a quartz particle. The photocatalytic activity of TiO on quartz particles grown by ALD was studied in terms of ALD growth temperature and post-treatment heating rate.
View Article and Find Full Text PDFHeliyon
January 2025
Department of Chemistry, Nazarbayev University, Astana, 010000, Kazakhstan.
The rapid growth in the global population has led to increased environmental pollution and energy demands, exacerbating the issue of environmental contamination. This contamination is significantly impacted by various types of pesticides found in water sources, which pose serious health risks to humans, animals, and aquatic ecosystems. In response, extensive research into water treatment technologies has been conducted, focusing on efficient methods to remove these pollutants, with advanced oxidation processes and the utilization of tungsten trioxide (WO) as a photocatalyst showing promising results.
View Article and Find Full Text PDFHeliyon
January 2025
Advanced Materials Research Laboratory, Department of Physics, Faculty of Science, University of Tabuk, Tabuk, Saudi Arabia.
Herein, we report the biosynthesis of pure NiO and NiO nanoparticles doped with Silver (Ag@NiO NPs) 2, 4, 6, and 8 mol% from aloe vera extract by solution combustion method at 400 °C and calcined at 500 °C for 3 h. By utilizing silver-doped NiO nanoparticles synthesized with Aloe Vera latex, which not only enhances the material's properties but also promotes environmentally friendly fabrication methods. The morphological, structural elemental compositions were analysed through SEM, HRTEM, SAED, XRD and EDAX.
View Article and Find Full Text PDFDalton Trans
January 2025
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, P.R. China.
Photocatalytic degradation of the azo dye orange II using NdVO/VO/BiVO under visible light is reported here, and this oxygen-rich defect three-phase heterojunction structure is constructed using a two-step cation exchange method. This heterojunction significantly enhances the separation and migration efficiency of photo-induced charges, while the accompanying oxygen defects effectively capture photogenerated electrons, thereby suppressing the recombination of electrons and holes. Experimental characterization and theoretical calculations demonstrate the efficient separation and transfer capabilities of photogenerated carriers and their excellent photocatalytic degradation performance.
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