Herein, we report a photoinduced sulfoximine-to-copper charge-transfer-enabled generation of sulfoximinyl radicals directly from -sulfoximines for C-H sulfoximination of arenes via radical addition. Through copper-LMCT, N-arylation of -sulfoximines was achieved for the first time using arenes of different electronic structures as the aryl donors.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9942232 | PMC |
| http://dx.doi.org/10.1021/acs.orglett.3c00256 | DOI Listing |
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