The anisotropy of liquid crystalline elastomers (LCEs) is derived from the interaction-facilitated orientation of the molecular constituents. Here, we correlate the thermomechanical response of a series of LCEs subjected to mechanical alignment to measurements of the Hermans orientation parameter. The LCEs were systematically prepared with varying concentrations of liquid crystalline mesogens, which affects the relative degree of achievable order. These compositions were subject to varying degrees of mechanical alignment to prepare LCEs with orientations that span a wide range of orientation parameters. The stimuli-response of the LCEs indicates that the liquid crystalline content defines the temperature of actuation, whereas the orientation parameter of the LCE is intricately correlated to both the total actuation strain of the LCE as well as the rate of thermomechanical response.
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