Rechargeable materials for the effective protection of dry food products were developed. β-cyclodextrin-thymol inclusion complex was covalently grafted on a solid platform of polyethylene terephthalate-viscose using either traditional cross-linker of epichlorohydrin, or natural cross-linker of citric acid. A correlation between the grafting method and physicochemical properties, loading capacity and release capabilities of the resulted materials was studied. The developed materials demonstrated antimicrobial properties preventing mold propagation in wheat grains. The treated grains showed normal germination abilities verifying that the prepared materials can protect dry food products without using harmful chemicals. The suggested approach can be extended to other applications and active agents. A combination of rechargeable films with natural volatiles can serve as an effective platform for sustainable active materials for food protection and in other fields such as agriculture, cosmetics, and medicine.
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http://dx.doi.org/10.1016/j.foodchem.2023.135560 | DOI Listing |
JACS Au
December 2024
Department of Materials Design Innovation Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Aichi, Japan.
Controlling the nucleation, growth, and dissolution of Li is crucial for the high cycling stability in rechargeable Li metal batteries. The overpotential for Li nucleation (η) on Li alloys such as Li-Au is generally lower than that on metal current collectors (CCs) with very limited Li solubility like Cu. However, the alloying process of CC and its impact on the Li nucleation kinetics remain unclear.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Faculty of Science, Yamagata University, 1-4-12 Kojirakawa-machi, Yamagata, Yamagata 990-8560, Japan.
Sustainable energy societies demand rechargeable batteries using ubiquitous-material electrodes of geopolitical-risk-free elements. We aim to develop low-overpotential oxygen-evolution-reaction (OER) catalysts that suppress carbon corrosion of gas-diffusion electrodes (GDEs) to realize two-electrode rechargeable Zn-air batteries (r-ZABs). Herein, single-walled-carbon-nanotube (SWNT) thin films are used as a scaffold for a benchmark OER catalyst, doping-free NiFe-layered double hydroxide (NiFeLDHs), operating in r-ZABs using alkali aqueous electrolytes.
View Article and Find Full Text PDFMater Horiz
October 2024
Hubei Longzhong Laboratory, Wuhan University of Technology Xiangyang Demonstration Zone, Xiangyang 441000, China.
Ultrathin nanofibrous films with unique properties, such as controlled thickness, structures, and excellent mechanical robustness, play a vital role in flexible wearable devices, electronic skin, and rechargeable batteries. However, nanofibrous films are always facing limitations in their mechanical properties, even though they are strong when used as textiles, mainly owing to their structural shortcomings by using conventional fabrication methods. Herein, we present the fabrication of free-standing ultrathin nanofibrous films with good mechanical properties by using a microfluidic-based continuous printing strategy.
View Article and Find Full Text PDFACS Appl Mater Interfaces
July 2024
Centre for Nano and Soft Matter Sciences, Bangalore, Karnataka 562162, India.
Angew Chem Int Ed Engl
July 2024
Department of Materials Science and Engineering, City University of Hong Kong, Kowloon, Hong Kong, SAR 999077, China.
Alkali metals (e.g. Li, Na, and K) and multivalent metals (e.
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