AI Article Synopsis
- A new series of organic dyes featuring a diquat moiety as an electron acceptor have been synthesized and characterized, with their properties supported by DFT calculations.
- These dyes were tested in the aerobic thiocyanation process involving indoles and pyrroles, demonstrating impressive photocatalytic activity under visible light, achieving yields of up to 97%.
- The study also discusses the photocatalytic performance of standalone diquat and methyl viologen and their interaction in forming an electron donor-acceptor complex.
Article Abstract
A series of new organic donor-π-acceptor dyes incorporating a diquat moiety as a novel electron-acceptor unit have been synthesized and characterized. The analytical data were supported by DFT calculations. These dyes were explored in the aerobic thiocyanation of indoles and pyrroles. Here they showed a high photocatalytic activity under visible light, giving isolated yields of up to 97 %. In addition, the photocatalytic activity of standalone diquat and methyl viologen through formation of an electron donor acceptor complex is presented.
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