In this study, methyl orange (MO) dye removal by adsorption utilizing activated carbon made from date seeds (DPAC) was modeled using an artificial neural network (ANN) technique. Instrumental investigations such as X-ray diffraction (XRD), scanning electron microscopy (SEM), and Brunauer-Emmett-Teller (BET) analysis were used to assess the physicochemical parameters of adsorbent. By changing operational parameters including adsorbent dosage (0.01-0.03 g), solution pH 3-8, initial dye concentration (5-20 mg/L), and contact time (2-60 min), the viability of date seeds for the adsorptive removal of methyl orange dye from aqueous solution was assessed in a batch procedure. The system followed the pseudo 2nd order kinetic model for DPAC adsorbent, according to the kinetic study (R2 = 0.9973). The mean square error (MSE), relative root mean square error (RRMSE), root mean square error (RMSE), mean absolute percentage error (MAPE), relative error (RE), and correlation coefficient (R) were used to measure the ANN model performance. The maximum RE was 8.24% for the ANN model. Two isotherm models, Langmuir and Freundlich, were studied to fit the equilibrium data. Compared with the Freundlich isotherm model (R = 0.72), the Langmuir model functioned better as an adsorption isotherm with R of 0.9902. Thus, this study demonstrates that the dye removal process can be predicted using an ANN technique, and it also suggests that adsorption onto DPAC may be employed as a main treatment for dye removal from wastewater.
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http://dx.doi.org/10.1016/j.heliyon.2023.e12888 | DOI Listing |
Anal Chim Acta
February 2025
Engineering Research Center of Optical Instrument and System, Ministry of Education and Shanghai Key Lab of Modern Optical System, University of Shanghai for Science and Technology, No.516 Jungong Road, Shanghai, 200093, China.
Background: Surface-enhanced Raman scattering (SERS) has attracted much attention as a powerful detection and analysis tool with high sensitivity and fast detection speed. The intensity of the SERS signal mainly depended on the highly enhanced electromagnetic field of nanostructure near the substrate. However, the fabrication of high-quality SERS nanostructured substrates is usually complicated, makes many methods unsuitable for large-scale production of SERS substrates.
View Article and Find Full Text PDFInt J Mol Sci
January 2025
Department of Mathematical, Physical and Computer Sciences, University of Parma, 43124 Parma, Italy.
This study presents an efficient and environmentally sustainable synthesis of ZnO nanoparticles using a starch-mediated sol-gel approach. This method yields crystalline mesoporous ZnO NPs with a hexagonal wurtzite structure. The synthesized nanoparticles demonstrated remarkable multifunctionality across three critical applications.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Istanbul Technical University, Faculty of Science and Letters, Department of Chemistry, Soft Materials Research Laboratory, 34469, Maslak, Istanbul, Turkey. Electronic address:
Controllable macromolecular architecture formation via polysaccharide integrated ternary copolymerization was explored in the design of amino-functionalized n-alkyl methacrylate ester-based biohybrids. Ternary poly(dimethylaminoethyl methacrylate-co-glycidyl methacrylate-co-hydroxypropyl methacrylate)/sodium-alginate, PDGH/ALG, hybrids were designed using anionic polysaccharide through in-situ radical polymerization. An insight into the effect of ALG on physicochemical structure of ternary hybrids, particularly the interactions between polymeric chains, was created.
View Article and Find Full Text PDFHeliyon
January 2025
College of Chemical Engineering, Zhejiang University of Technology, China.
Titania (TiO) is one of promising photo catalysts for its high ability to resistant photo corrosion and environmental friendliness, but its photocatalytic activity is too low to be used in industry. To find an approach to solve this problem, graphene oxide (GO), tungsten trioxide (WO) and TiO composite with hollow mesoporous structure was prepared by a two-step spray drying method. The composite was used as raw material to constitute a membrane onto ITO glass to form a membrane photo-anode.
View Article and Find Full Text PDFLangmuir
January 2025
Cancer Molecular Diagnostics Core, Tianjin Medical University Cancer Institute and Hospital, National Clinical Research Center for Cancer, State Key Laboratory of Druggability Evaluation and Systematic Translational Medicine, Tianjin's Clinical Research Center for Cancer, Key Laboratory of Cancer Immunology and Biotherapy, Tianjin 300060, China.
Adsorbents with high selectivity and adsorption capacity are of significant interest for the removal of dye pollutants. Herein, we report a facile low-temperature solvothermal synthesis of clew-like CuO/CuO microspheres by using cupric acetate monohydrate as the copper resource and ethylene glycol as the solvent and morphology modulator. The synthesized CuO/CuO microspheres showed high selective adsorption to anionic dyes (e.
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