Fabrication of a Biomass-Derived Activated Carbon-Based Anode for High-Performance Li-Ion Batteries.

Porous carbons are highly attractive and demanding materials which could be prepared using biomass waste; thus, they are promising for enhanced electrochemical capacitive performance in capacitors and cycling efficiency in Li-ion batteries. Herein, biomass (rice husk)-derived activated carbon was synthesized via a facile chemical route and used as anode materials for Li-ion batteries. Various characterization techniques were used to study the structural and morphological properties of the prepared activated carbon. The prepared activated carbon possessed a carbon structure with a certain degree of amorphousness. The morphology of the activated carbon was of spherical shape with a particle size of ~40-90 nm. Raman studies revealed the characteristic peaks of carbon present in the prepared activated carbon. The electrochemical studies evaluated for the fabricated coin cell with the activated carbon anode showed that the cell delivered a discharge capacity of ~321 mAhg at a current density of 100 mAg for the first cycle, and maintained a capacity of ~253 mAhg for 400 cycles. The capacity retention was found to be higher (~81%) with 92.3% coulombic efficiency even after 400 cycles, which showed excellent cyclic reversibility and stability compared to commercial activated carbon. These results allow the waste biomass-derived anode to overcome the problem of cyclic stability and capacity performance. This study provides an insight for the fabrication of anodes from the rice husk which can be redirected into creating valuable renewable energy storage devices in the future, and the product could be a socially and ethically acceptable product.