ZnO and Ti-doped ZnO (Ti-ZnO) nanoparticles were synthesized using rapid combustion. The morphology of ZnO and Ti-ZnO featured nanoparticles within cluster-like structures. The ZnO and Ti-ZnO structures exhibited similar hexagonal wurtzite structures and crystal sizes. This behavior occurred because Zn sites of the ZnO lattice were substituted by Ti ions. The chemical structure characterization implied the major vibration of the ZnO structure. The physisorption analysis showed similar mesoporous and non-rigid aggregation structures for ZnO and Ti-ZnO using N adsorption-desorption. However, Ti-ZnO demonstrated a specific surface area two times higher than that of ZnO. This was a major factor in improving the photocatalytic degradation of methylene blue (MB). The photocatalytic degradation analysis showed a kinetic degradation rate constant of 2.54 × 10 min for Ti-ZnO, which was almost 80% higher than that of ZnO (1.40 × 10 min). The transformation mechanism of MB molecules into other products, including carbon dioxide, aldehyde, and sulfate ions, was also examined.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9865418PMC
http://dx.doi.org/10.3390/toxics11010033DOI Listing

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