ZnO and Ti-doped ZnO (Ti-ZnO) nanoparticles were synthesized using rapid combustion. The morphology of ZnO and Ti-ZnO featured nanoparticles within cluster-like structures. The ZnO and Ti-ZnO structures exhibited similar hexagonal wurtzite structures and crystal sizes. This behavior occurred because Zn sites of the ZnO lattice were substituted by Ti ions. The chemical structure characterization implied the major vibration of the ZnO structure. The physisorption analysis showed similar mesoporous and non-rigid aggregation structures for ZnO and Ti-ZnO using N adsorption-desorption. However, Ti-ZnO demonstrated a specific surface area two times higher than that of ZnO. This was a major factor in improving the photocatalytic degradation of methylene blue (MB). The photocatalytic degradation analysis showed a kinetic degradation rate constant of 2.54 × 10 min for Ti-ZnO, which was almost 80% higher than that of ZnO (1.40 × 10 min). The transformation mechanism of MB molecules into other products, including carbon dioxide, aldehyde, and sulfate ions, was also examined.
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http://dx.doi.org/10.3390/toxics11010033 | DOI Listing |
Acta Biomater
February 2024
Research Center for Computer-Aided Drug Discovery, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China. Electronic address:
Conventional Ti-based implants are vulnerable to postsurgical infection and improving the antibacterial efficiency without compromising the osteogenic ability is one of the key issues in bone implant design. Although zinc oxide (ZnO) nanorods grown on Ti substrates hydrothermally can improve the antibacterial properties, but cannot meet the stringent requirements of bone implants, as rapid degradation of ZnO and uncontrolled leaching of Zn are detrimental to peri-implant cells and tissues. To solve these problems, a lattice-damage-free method is adopted to modify the ZnO nanorods with thin calcium phosphate (CaP) shells.
View Article and Find Full Text PDFToxics
December 2022
Department of Physics, Faculty of Liberal Arts and Science, Kasetsart University Kamphaeng Saen Campus, Kamphaeng Saen, Nakhon Pathom 73140, Thailand.
ZnO and Ti-doped ZnO (Ti-ZnO) nanoparticles were synthesized using rapid combustion. The morphology of ZnO and Ti-ZnO featured nanoparticles within cluster-like structures. The ZnO and Ti-ZnO structures exhibited similar hexagonal wurtzite structures and crystal sizes.
View Article and Find Full Text PDFPLoS One
June 2022
School of Chemical and Physical Science, Victoria University of Wellington, Wellington, New Zealand.
Microelectrodes are commonly used in electrochemical analysis and biological sensing applications owing to their miniaturised dimensions. It is often desirable to improve the performance of microelectrodes by reducing their electrochemical impedance for increasing the signal-to-noise of the recorded signals. One successful route is to incorporate nanomaterials directly onto microelectrodes; however, it is essential that these fabrication routes are simple and repeatable.
View Article and Find Full Text PDFChemosphere
May 2021
Department of Chemical Engineering, Universidad de Castilla-La Mancha, Campus Universitario S/n, 13071, Ciudad Real, Spain. Electronic address:
In this work, it is proposed a novel strategy to increase the photostability of the ZnO photoelectrocatalyst under prolonged light irradiation, without the addition or deposition of metals and/or semiconductor oxides during their synthesis. This strategy is based on the use of a mixed metal oxide (MMO-RuTiO) coating as the substrate for the electrodeposition of ZnO. To assess it, the electrodeposition of ZnO films on Ti and Ti/MMO substrates and the photoelectrocatalytic activity of these materials for the degradation of the herbicide clopyralid were studied.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2020
Materials and Components Research Division , Electronics and Telecommunications Research Institute (ETRI), 218 Gajeong-ro , Yuseong-gu, Daejeon 34129 , Republic of Korea.
Two-dimensional transition metal dichalcogenides (TMDCs) have emerged as promising materials for next-generation electronics due to their excellent semiconducting properties. However, high contact resistance at the metal-TMDC interface plagues the realization of high-performance devices. Here, an effective metal-interlayer-semiconductor (MIS) contact is demonstrated, wherein an ultrathin ZnO interlayer is inserted between the metal electrode and MoS, providing damage-free and clean interfaces at electrical contacts.
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