The dynamics of levitated liquid droplets can be used to measure their thermophysical properties by correlating the frequencies at which normal modes of oscillation most strongly resonate when subject to an external oscillatory force. In two preliminary works, it was shown via electrostatic levitation and processing of various metals and alloys that (1) the resonance of the first principal mode of oscillation (mode n = 2) can be used to accurately measure surface tension and (2) that so-called "higher-order resonance" of n = 3 is observable at a predictable frequency. It was also shown, in the context of future space-based experimentation on the Electrostatic Levitation Furnace (ELF), a setup on the International Space Station (ISS) operated by Japan Aerospace Exploration Agency (JAXA), that while the shadow array method in which droplet behavior is visualized would be challenging to identify the n = 3 resonance, the normal mode n = 4 was predicted to be more easily identifiable. In this short communication, experimental evidence of the first three principal modes of oscillation is provided using molten samples of Tin and Indium and it is subsequently shown that, as predicted, an "image-less" approach can be used to identify both n = 2 and n = 4 resonances in levitated liquid droplets. This suggests that the shadow array method may be satisfactorily used to obtain a self-consistent benchmark of thermophysical properties by comparing results from two successive even-mode natural frequencies.
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http://dx.doi.org/10.1038/s41526-023-00254-7 | DOI Listing |
Materials (Basel)
December 2024
Interfaces, Confinement, Matériaux et Nanostructures, 45071 Orléans Cedex 2, France.
Magnesium aluminates (MgO)(AlO) belong to a class of refractory materials with important applications in glass and glass-ceramic technologies. Typically, these materials are fabricated from high-temperature molten phases. However, due to the difficulties in making measurements at very high temperatures, information on liquid-state structure and properties is limited.
View Article and Find Full Text PDFEntropy (Basel)
September 2024
Department of Mechanical Engineering (Materials Science and Engineering Program), University of California, Riverside, CA 92521, USA.
This study investigates the impact of cooling rate and alloy composition on phase formations and properties of (CoCrCuTi)Fe (x = 0, 5, 10, 12.5, 15) high-entropy alloys (HEAs). Samples were synthesized using arc-melting and electromagnetic levitation, followed by quenching through the use of a Cu chill or V-shaped Cu mold.
View Article and Find Full Text PDFPhys Rev E
September 2024
School of Physical Science and Technology, Northwestern Polytechnical University, Xi'an 710072, China.
The liquid state thermophysical properties and amorphous solidification kinetics of Fe_{50-x}Co_{x}Cr_{14}Mo_{14}C_{9}B_{8}Tm_{5} (x=10, 15, 20, and 25) alloys were explored by electromagnetic and electrostatic levitation techniques. It was found that the surface tension of liquid alloys with Fe contents below 30 at. % had a strong temperature dependence.
View Article and Find Full Text PDFJ Am Chem Soc
October 2024
College of Chemistry, Frontiers Science Center for New Organic Matter, State Key Laboratory of Advanced Chemical Power Sources, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Tianjin Key Laboratory of Biosensing and Molecular Recognition, Renewable Energy Conversion and Storage Center (ReCAST), Nankai University, Tianjin, 300071, China.
Microdroplet chemistry is now well-known to be able to remarkably accelerate otherwise slow reactions and trigger otherwise impossible reactions. The uniqueness of the microdroplet is attributable to either the air-water interface or solid-liquid interface, depending on the medium that the microdroplet is in contact with. To date, the importance of the solid-liquid interface might have been confirmed, but the contribution from the air-water interface seems to be elusive due to the lack of method for generating contactless microdroplets.
View Article and Find Full Text PDFJ Phys Chem A
October 2024
X-BIO Institute, University of Tyumen, Tyumen 625003, Russia.
It has been reported that the self-assembly pattern of light levitating droplet clusters above the hot gas-liquid interface is dependent on the quantity of droplets. However, the already-reported theoretical explanation of the quantity-dependent self-assembly pattern cannot work well when the quantity of the light levitating droplet exceeds 15. Herein, we propose a new theoretical perspective to understand the self-assembly of a light levitating droplet cluster by referring to the classical densest packing problem of identical rigid circles in a larger circle with the introduction of the minimum total potential energy principle.
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