Ni-Catalyzed Regioselective Reductive 1,3-Dialkenylation of Alkenes.

ACS Omega

Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, United States.

Published: January 2023

Dicarbofunctionalization is an important efficient synthetic technique for adding two chemical moieties across an alkene. Here, a novel method of reductive dicarbofunctionalization has been developed using a single alkenyl triflate as the electrophile, combined with an unactivated alkene. The reaction does not require an external auxiliary and proceeds with complete regioselectivity.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9835523PMC
http://dx.doi.org/10.1021/acsomega.2c06417DOI Listing

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