AI Article Synopsis

  • The study examines how different aging methods impact the optical and crystalline properties of high-translucency zirconia.
  • Thirty-six zirconia specimens were tested under no treatment, hydrothermal aging, and clinically related aging, with various analyses conducted to determine effects on translucency and structure.
  • Results showed that while hydrothermal aging influenced the crystalline structure of HT-zirconia, clinically related aging primarily affected optical properties, with no significant changes in translucency or surface roughness observed.

Article Abstract

Purpose: To investigate the effect of different in vitro aging protocols on the optical properties and crystalline structure of high-translucency (HT) zirconia.

Materials And Methods: Thirty-six specimens of HT and extra-high translucency (XT) zirconia were divided into three groups: control (CO)-no treatment; hydrothermal aging (HA)-autoclave aging for 12.5 h at 134°C, 2 bar; clinically related aging (CRA)-aging in the chewing simulator for 1.2 million cycles, followed by 50,000 thermocycles (5-55°C) and immersion in HCl (pH 1.2) for 15 h. Optical properties, crystalline structure, and surface roughness were analyzed and compared using analysis of variance (5% significance level).

Results: There was no statistically significant effect of aging on translucency (p = 0.10), but CRA promoted the development of a high contrast ratio (p = 0.03). Aging did not cause significant color changes for HT (p = 0.65) or XT (p = 0.36). The proportion of monoclinic crystals increased to 40% for HT-zirconia after HA and 5% after CRA. No monoclinic crystals were detected for XT groups. There was no effect of aging on surface roughness (p = 0.77).

Conclusions: Although hydrothermal aging has been widely used to verify zirconia crystalline stability, it did not generate an effect similar to clinically related aging on the optical properties and crystalline structure of zirconia. HA affected the crystalline structure of HT-zirconia, and CRA compromised the optical properties of XT zirconia.

Download full-text PDF

Source
http://dx.doi.org/10.1111/jopr.13648DOI Listing

Publication Analysis

Top Keywords

optical properties
20
crystalline structure
20
properties crystalline
16
aging
9
aging optical
8
structure high-translucency
8
hydrothermal aging
8
clinically aging
8
surface roughness
8
monoclinic crystals
8

Similar Publications

Manipulating the optical landscape of single quantum dots (QDs) is essential to increase the emitted photon output, enhancing their performance as chemical sensors and single-photon sources. Micro-optical structures are typically used for this task, with the drawback of a large size compared to the embedded single emitters. Nanophotonic architectures hold the promise to modify dramatically the emission properties of QDs, boosting light-matter interactions at the nanoscale, in ultracompact devices.

View Article and Find Full Text PDF

Currently, the development of red Mn-activated fluoride luminescent materials attracts a lot of attention in optical thermometry sensors, solid lighting, display, and plant growth areas. Nevertheless, the thermal stability of Mn-activated fluoride luminescent materials is still a crucial issue. Herein, a new red RbNaVF:Mn luminescent material with outstanding thermal stability was successfully synthesized through the facial coprecipitation method.

View Article and Find Full Text PDF

Electrically Switchable Multi-Stable Topological States Enabled by Surface-Induced Frustration in Nematic Liquid Crystal Cells.

Adv Mater

January 2025

Liquid Crystals and Photonics Group, Department of Electronics and Information Systems, Ghent University, Technologiepark-Zwijnaarde 126, Ghent, 9052, Belgium.

In liquid crystal (LC) cells, the surface patterning directs the self-assembly of the uniaxial building blocks in the bulk, enabling the design of stimuli-response optical devices with various functionalities. The combination of different anchoring patterns at both substrates can lead to surface induced frustration, preventing a purely planar and defect-free configuration. In cells with crossed assembly of rotating anchoring patterns, elastic deformations allow to obtain a defect-free bulk configuration, but an electrical stimulus can induce disclination lines.

View Article and Find Full Text PDF

Co-assemblies of Silver Nanoclusters and Fullerenols With Enhanced Third-Order Nonlinear Optical Response.

Small Methods

January 2025

National Engineering Research Center for Colloidal Materials, Key Laboratory of Colloid and Interface Chemistry (Ministry of Education), School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, China.

Exploring potential third-order nonlinear optical (NLO) materials attracts ever-increasing attention. Given that the atomically precise and rich adjustable structural features of silver nanoclusters (Ag NCs), as well as the unique π-electron conjugated system of carbon-based nanomaterials, a supramolecular co-assembly amplification strategy to enhance the luminescent intensity and NLO performance of the hybrids of the two components, are constructed and the relationship between structures and optical properties are investigated. By combining water soluble Ag NCs [(NH)[Ag(mna)] (Hmna = 2-mercaptonicotinic acid, abbreviated to Ag─NCs hereafter) containing uncoordinated carboxyl groups with water-soluble fullerene derivatives modified with multiple hydroxyl groups (fullerenols, C─OH), the π-electron delocalization is expanded owing to non-covalent hydrogen bonding effect between Ag6─NCs and C─OH, which provides a feasible basis for realizing the NLO response.

View Article and Find Full Text PDF

: Diabetes is a well-recognised factor inducing a plethora of corneal alterations ranging from dry eye to reduced corneal sensibility, epithelial defects, and reduced cicatrisation. This cohort study aimed to assess the efficacy of a novel ophthalmic solution combining cross-linked hyaluronic acid (CHA), chondroitin sulfate (CS), and inositol (INS) in managing diabetes-induced corneal alterations. Specifically, it evaluated the solution's impact on the tear breakup time (TBUT), the ocular surface disease index (OSDI), and corneal sensitivity after three months of treatment.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!