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Singlet Oxygen Responsive Molecular Receptor to Modulate Atropisomerism and Cation Binding. | LitMetric
In switchable molecular recognition, O stimulus responsive receptors offer a unique structural change that is rarely exploited. The employed [4+2] reaction between O and anthracene derivatives is quantitative, reversible and easily implemented. To evaluate the full potential of this new stimulus, a non-macrocyclic anthracene-based host was designed for the modular binding of cations. The structural investigation showed that O controlled the atropisomerism in an on/off fashion within the pair of hosts. The binding studies revealed higher association constants for the endoperoxide receptor compared to the parent anthracene, due to a more favoured preorganization of the recognition site. The fatigue of the O switchable hosts and their complexes was monitored over five cycles of cycloaddition/cycloreversion.
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