Based on the effective Schrödinger-Poisson model a new physical mechanism for resonant hot-electron generation at irradiated half-space metal-vacuum interface of electron gas with arbitrary degree of degeneracy is proposed. The energy dispersion of undamped plasmons in the coupled Hermitian Schrödinger-Poisson system reveals an exceptional point coinciding the minimum energy of plasmon conduction band. Existence of such exceptional behavior is a well-know character of damped oscillation which in this case refers to resonant wave-particle interactions analogous to the collisionless Landau damping effect. The damped Schrödinger-Poisson system is used to model the collective electron tunneling into the vacuum. The damped plasmon energy dispersion is shown to have a full-featured exceptional point structure with variety of interesting technological applications. In the band gap of the damped collective excitation,depending on the tunneling parameter value, there is a resonant energy orbital for which the wave-like growing of collective excitations cancels the damping of the single electron tunneling wavefunction. This important feature is solely due to dual-tone wave-particle oscillations, characteristics of the collective excitations in the quantum electron system leading to a resonant photo-plasmonic effect, as a collective analog of the well-known photo-electric effect. The few nanometer wavelengths high-energy collective photo-electrons emanating from the metallic surfaces can lead to a much higher efficiency of plasmonic solar cell devices, as compared to their semiconductor counterpart of electron-hole excitations at the Fermi energy level. The photo-plasmonic effect may also be used to study the quantum electron tunneling and electron spill-out at metallic surfaces. Current findings may help to design more efficient spasers by using the feature-rich plasmonic exceptional point structure.
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http://dx.doi.org/10.1038/s41598-023-27775-1 | DOI Listing |
Anal Methods
January 2025
Key Laboratory of Biorheological Science and Technology, Ministry of Education, College of Bioengineering, Chongqing University, Chongqing 400044, PR China.
Methotrexate (MTX), a widely administered medication for treating an array of tumors and autoimmune disorders, necessitates stringent monitoring due to the potential for severe adverse effects associated with its high dosage. Nevertheless, the existing methods for monitoring MTX are often intricate, time-consuming and incur significant costs. In this work, we constructed a controlled release sensor, harnessing the versatility of a personal glucose meter (PGM), which had been devised for the swift detection of MTX.
View Article and Find Full Text PDFAnal Chim Acta
February 2025
Key Laboratory of Water Security and Water Environment Protection in Plateau Intersection (NWNU), Ministry of Education, Key Lab of Bioelectrochemistry and Environmental Analysis of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, 730070, Lanzhou, Gansu, China. Electronic address:
Background: Reliable and selective detection of dopamine is crucial for the early diagnosis of various diseases. Transition metal based-nanozymes have shown great promise in the field of colorimetric detection of dopamine due to their remarkable stability and exceptional catalytic efficiency. However, these transition metal-based nanozymes typically function through a chromogenic reaction that relies on additional organic substrates, such as 3,3',5,5'-tetramethylbenzidine, to generate a detectable signal.
View Article and Find Full Text PDFAppl Microbiol Biotechnol
January 2025
Department of Chemical Engineering, University of California, Santa Barbara, CA, 93106, USA.
The animal gut microbiome is a complex system of diverse, predominantly anaerobic microbiota with secondary metabolite potential. These metabolites likely play roles in shaping microbial community membership and influencing animal host health. As such, novel secondary metabolites from gut microbes hold significant biotechnological and therapeutic interest.
View Article and Find Full Text PDFMater Horiz
January 2025
Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin, 300350, P. R. China.
Conductive hydrogels with stable sensing performance are highly required in soft electronic devices. However, these hydrogels tend to solidify and experience structural damage at sub-zero temperatures, leading to material breakdown and device malfunction. The main challenge lies in effectively designing the micro/nano-structure to enhance mechanical properties and stable strain sensing while preventing freezing in hydrogels.
View Article and Find Full Text PDFImportance: "SuperAgers" are oldest-old adults (ages 80+) whose memory performance resembles that of adults in their 50s to mid-60s. Factors underlying their exemplary memory are underexplored in large, racially diverse cohorts.
Objective: To determine the frequency of genotypes in non-Hispanic Black and non-Hispanic White SuperAgers compared to middle-aged (ages 50-64), old (ages 65-79), and oldest-old (ages 80+) controls and Alzheimer's disease (AD) dementia cases.
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