Tris(benzyl-diphenyl-phosphane-κ)(nitrato-κ)silver(I).

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Department of Chemical Sciences, University of Johannesburg, PO Box 524, Auckland Park, 2006, Johannesburg, South Africa.

Published: December 2022

The mol-ecular structure of the title complex, [Ag(NO)(CHP)], exhibits a severely distorted tetra-hedral coordination environment around the central Ag atom, comprising one O and three P atoms. Apart from a primary Ag-O coordination of the nitrato ligand of 2.667 (3) Å, a second (weaker) secondary inter-action of the nitrato ligand the other O atom of 3.118 (4) Å is observed. The compound crystallizes with a complete mol-ecule in the asymmetric unit. Weak C-H⋯O inter-actions consolidate the packing.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815128PMC
http://dx.doi.org/10.1107/S2414314622011476DOI Listing

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