Solid particle erosion at room and elevated temperatures of filled and unfilled hot-cured epoxy resin using an anhydride hardener were experimentally tested using an accelerated method on a special bench. Micro-sized dispersed industrial wastes were used as fillers: fly ash from a power plant and spent filling material from a copper mining and processing plant. The results showed that the wear of unfilled epoxy resin significantly decreases with increasing temperature, while the dependence on the temperature of the wear intensity at an impingement angle of 45° is linear and inversely proportional, and at an angle of 90°, non-linear. The decrease in wear intensity is probably due to an increase in the fracture limit because of heating. Solid particle erosion of the filled epoxy compounds is considerably higher than that of unfilled compounds at impingement angles of 45° and 90°. Filled compounds showed ambiguous dependences of the intensity of wear on temperature (especially at an impingement angle of 45°), probably as the dependence is defined by the filler share and the structural features of the samples caused by the distribution of filler particles. The intensity of the wear of the compounds at impingement angles of 45° and 90° has a direct and strong correlation with the density and the modulus of elasticity, and a weak correlation with the bending strength of the materials. The data set for determining the correlation between the mechanical properties and the wear included compound filling characteristics and temperature.
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http://dx.doi.org/10.3390/polym15010001 | DOI Listing |
Nanomaterials (Basel)
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Personalized Medicine Centre, Almazov National Medical Research Centre, Akkuratova Str. 2, 197341 St. Petersburg, Russia.
This study addresses issues in developing spatially controlled magnetic fields for particle guidance, synthesizing biocompatible and chemically stable MNPs and enhancing their specificity to pathological cells through chemical modifications, developing personalized adjustments, and highlighting the potential of tumor-on-a-chip systems, which can simulate tissue environments and assess drug efficacy and dosage in a controlled setting. The research focused on two MNP types, uncoated magnetite nanoparticles (mMNPs) and carboxymethyl dextran coated superparamagnetic nanoparticles (CD-SPIONs), and evaluated their transport properties in microfluidic systems and porous media. The original uncoated mMNPs of bimodal size distribution and the narrow size distribution of the fractions (23 nm and 106 nm by radii) were demonstrated to agglomerate in magnetically driven microfluidic flow, forming a stable stationary web consisting of magnetic fibers within 30 min.
View Article and Find Full Text PDFWaste Manag Res
December 2024
Chair of Waste Processing Technology and Waste Management, Department of Environmental and Energy Process Engineering, Montanuniversitaet Leoben, Leoben, Austria.
This article uses model materials to introduce a controlled, location- and manufacturer-independent internationally accepted method for assessing shredding machines based on large-scale tests. Furthermore, a better understanding of the comminution behaviour of shredders with fixed settings (gap width, shaft speed, cutting tool geometry) is in the focus of the present investigation and assessed, using the statistical analyses for particle size distribution in certain screen sections. Conclusions have been drawn on the comminution behaviour in general and the material-material interactions of different fractions in the grinding chamber of the shredder by showing significant differences in the pure fraction's comminution behaviour against the mixture's comminution behaviour.
View Article and Find Full Text PDFGels
December 2024
Chemistry Department, Faculty of Science, Taibah University, Medina Munwarah 42353, Saudi Arabia.
This work presents a novel hydrothermally aided sol-gel method for preparation of mesoporous silica nanoparticles (MSNs) with a narrow particle size distribution and varied pore sizes. The method was carried out in alkaline media in presence of polyethylene glycol (PEG) and cetyltrimethylammonium chloride (CTAC) as dual templates and permitted the synthesis of spherical mesoporous silica with a high surface area (1011.42 m/g).
View Article and Find Full Text PDFGels
December 2024
School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China.
During deepwater drilling, the low mudline temperatures and narrow safe density window pose serious challenges to the safe and efficient performance of deepwater water-based drilling fluids. Low temperatures can lead to physical and chemical changes in the components of water-based drilling fluids and the behavior of low temperature gelation. As a coarse dispersion system, water-based drilling fluid has a complex composition of dispersed phase and dispersing medium.
View Article and Find Full Text PDFBMC Chem
December 2024
School of Chemical and Environmental Engineering, International University, Quarter 6, Linh Trung Ward, Thu Duc City, Ho Chi Minh City, Vietnam.
Magnetic activated carbon has been proved its separation ability to overcome a main drawback of activated carbon powder. However, effect of magnetization method on characterizations and Chromium (VI) adsorption of this adsorbent from Artocarpus Heterophyllus Peel (jackfruit peel) has not been investigated yet. This study magnetized jackfruit peel activated carbon using thermochemical and co-precipitation methods.
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