Photocatalysis of Cr- and Fe-Doped CeO Nanoparticles to Selective Oxidation of 5-Hydroxymethylfurfural.

Nanomaterials (Basel)

Department of Chemistry, Yeungnam University, Daehak-ro 280, Gyeongsan, Gyeongbuk 38541, Republic of Korea.

Published: December 2022

Oxygen vacancies () present in CeO nanoparticles (NPs) can effectively boost their photocatalytic activity under ultraviolet (UV) light. To improve photocatalytic performance, Cr- and Fe-doped CeO NPs with increased were prepared using a simple method of doping Cr and Fe ions into CeO NPs, which was confirmed by an in-depth analysis of the structural and electronic changes. Through photocatalytic degradation (PCD) experiments with 5-hydroxymethylfurfural (HMF), we found that the PCD rates of the two doped CeO NPs were faster than that of the CeO NPs. In addition, the conversion of HMF to 2,5-furandicarboxylic acid (FDCA) using the doped CeO NPs occurred only through the mechanism of the selective oxidation to 5-hydroxymethyl-2-furancarboxylic acid (HMFCA), exhibiting better efficiency than using CeO NPs.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9823449PMC
http://dx.doi.org/10.3390/nano13010044DOI Listing

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