The synthesis of structured MgO is reported using feedstock starch (route I), citrus pectin (route II), and (route III) leaf, which are suitable for use as green fuels due to their abundance, low cost, and non-toxicity. The oxides formed showed high porosity and were evaluated as antimicrobial agents. The samples were characterized by energy-dispersive X-ray fluorescence (EDXRF), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). The crystalline periclase monophase of the MgO was identified for all samples. The SEM analyses show that the sample morphology depends on the organic fuel used during the synthesis. The antibacterial activity of the MgO-St (starch), MgO-CP (citrus pectin), and MgO-Av ( oxides was evaluated against pathogens (ATCC 6538P) and (ATCC 8739). Antifungal activity was also studied against (ATCC 64548). The studies were carried out using the qualitative agar disk diffusion method and quantitative minimum inhibitory concentration (MIC) tests. The MIC of each sample showed the same inhibitory concentration of 400 µg. mL for the studied microorganisms. The formation of inhibition zones and the MIC values in the antimicrobial analysis indicate the effective antimicrobial activity of the samples against the test microorganisms.
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http://dx.doi.org/10.3390/molecules28010142 | DOI Listing |
J Mol Graph Model
December 2024
Center of Excellence African on future Energies and Systems Electrochemical (ACE-FUELS), University Federal Technology, PMB 1526, Owerri, State from Imo, Nigeria.
Computational techniques have been used to analyze the molecules of 10-hydroxycoronahydine (HC) and voacangine hydroxyindolenine (VH) molecules with the aim of studying the effect of base and temperature on their interaction mechanisms during synthesis green magnetite nanoparticles. Density functional theory (DFT) descriptors such as: energy gap, overall reactivity descriptors, dipole moment and adsorption energy have all been explored in depth to understand the nature of the interaction. The DFT results showed that the molecules studied (HC and VH) are interactive and stable in an aqueous medium, due to the fact that these molecules have free electronic doublets on the nitrogen atom and the bond of the aromatic ring.
View Article and Find Full Text PDFEnergy Fuels
December 2024
Department of Chemistry, University of Burgos, 09001 Burgos, Spain.
The urge to adopt cleaner technologies drives the search for novel and sustainable materials such as Hydrophobic Natural Deep Eutectic Solvents (HNADESs), a new class of green solvents characterized by their low toxicity, biodegradability, and tunable properties, aiming to be applied in various fields for handling non-polar substances. In this work, the solubilization of hydrocarbons in type V HNADESs (non-ionic organic molecules) formed by mixing carvone, a natural monoterpenoid, with organic acids (hexanoic to decanoic acids) is examined by applying both experimental and theoretical approaches. The synthesis and physicochemical characterization of different HNADESs allowed us to tailor their properties, aiming for optimal interactions with desired hydrocarbons.
View Article and Find Full Text PDFHeliyon
December 2024
GPCHEM, Laboratory of Biogas Research and Analysis & Technology Incubator, Ul. Legionów 40a/3, 87-100 Toruń, Poland.
Both the global and European energy sectors have been undergoing a deep transition for several years, associated with a reduction in the overall share of conventional coal-based energy in favor of new technologies, especially energy from renewable sources (RES). This transition is moving from centralized production towards distributed technologies and from providing only energy to end users towards combining innovative products and services with it. Electricity consumers are becoming prosumers connected to the grid and generating an increasing amount of energy.
View Article and Find Full Text PDFSmall
December 2024
Key Laboratory for Green Organic Synthesis and Application of Hunan Province, Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, 411105, P. R. China.
The use of sunlight to convert CO into multi-carbon fuels, particularly propylene, is considered a sustainable carbon cycle pathway, but propylene requires a multi-electron-coupled proton reaction process that has not been reported. Herein, two covalent organic frameworks (DA-COF and DP-COF) are prepared by varying the bridging positions of anthraquinone conjugated units. The experimental results show that the neighbouring bridge in DA-COF forms a unique cleavage structure like an enzyme catalyst, which can provide an efficient microenvironment for the reduction reaction to trap protons.
View Article and Find Full Text PDFOrg Lett
December 2024
Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-Forest Biomass, Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, International Innovation Center for Forest Chemicals and Materials, College of Chemical Engineering, Nanjing Forestry University, Nanjing, Jiangsu 210037, China.
We herein report the efficient synthesis of peptide-benzazepine conjugates from Lys-based peptides and acroleins via Rh(III)-catalyzed double C-H activation. This reaction features mild reaction conditions, broad scope, high atom and step economies, and excellent chemo- and site selectivity. The synthetic utility of this strategy is further demonstrated by scale-up experiments and product derivatizations, including diverse late-stage ligations based on the aldehyde moiety.
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