Dzyaloshinskii-Moriya interaction (DMI), one of antisymmetric exchanges, originates from the combination of low structural symmetry and large spin-orbit coupling and favors magnetization rotations with fixed chirality. Herein, this work reports a DMI-like behavior in permalloy via coupled vortices in confined structures. Under the in-plane magnetic fields, continuous reversals of different coupled vortices are directly observed by in situ Lorentz transmission electron microscopy, and reproduced by complementary micromagnetic simulations. The statistical results show that coupled vortices with opposite chirality appear more frequently with the frequency up to about 60%. Such an asymmetric phenomenon mainly arises from a DMI-like behavior, associated with the increased total energy difference between different ground-state coupled vortices. Moreover, in the reversal process, the junction between disks accelerates the annihilation of vortices moving toward it and is also the starting point of vortex nucleation. These results provide an effective method to generate a DMI-like behavior in magnetic systems with symmetry breaking surface and benefit the future development of vortex-based spintronic devices.
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http://dx.doi.org/10.1002/smll.202207206 | DOI Listing |
Org Process Res Dev
January 2025
School of Chemistry, The University of Nottingham, University Park, Nottingham NG7 2RD, U.K.
We report the development and optimization of a scalable flow process for metallaphotoredox (Ir/Ni) C-O coupling, a mild and efficient approach for forming alkyl-aryl ethers, a common motif in medicinal and process chemistry settings. Time-resolved infrared spectroscopy (TRIR) highlighted the amine as the major quencher of the photocatalyst triplet excited state, along with the formation of an Ir(II) species that, in the presence of the Ni cocatalyst, has its lifetime shortened, suggesting reductive quenching of Ir(III)*, followed by reoxidation facilitated by the Ni cocatalyst. TRIR and batch reaction screening was used to develop conditions transferrable to flow, and many processing benefits of performing the reaction in flow were then demonstrated using a simple to construct/operate, small-footprint FEP coil flow reactor, including short (<10 min) space times and reduced catalyst loadings (down to 0.
View Article and Find Full Text PDFAnal Chem
January 2025
Shanxi Key Lab for Modernization of TCVM, College of Veterinary Medicine, Shanxi Agricultural University, Taiyuan 030000, Shanxi, P. R. China.
Microfluidics is an emerging technology for buffer exchange in bioprocessing applications. However, achieving buffer exchange with simplicity of operation and high throughput in a straightforward channel design remains a challenge. This study presents a novel semicircular microchannel design that allows for the deterministic regulation of helical and Dean vortices through geometric confinement.
View Article and Find Full Text PDFComput Biol Med
January 2025
UCL Mechanical Engineering, University College London, UK; Ri.MED Foundation, Palermo, Italy; University of Palermo, Department of Engineering, Palermo, Italy. Electronic address:
Aortic valve replacements, both surgical and transcatheter, are nowadays widely employed treatments. Although clinically effective, these procedures are correlated with potentially severe clinical complications which can be associated with the non-physiological haemodynamics that they establish. In this work, the fluid dynamics changes produced by surgical and transcatheter aortic valve replacements are analysed and compared with an ideal healthy native valve configuration, employing advanced fluid-structure interaction (FSI) simulations.
View Article and Find Full Text PDFBioinspir Biomim
January 2025
Intelligent Robotics Institute, School of Mechatronical Engineering, Beijing Institute of Technology, Beijing 100081, People's Republic of China.
The wings of birds contain complex morphing mechanisms that enable them to perform remarkable aerial maneuvers. Wing morphing is often described using five wingbeat motion parameters: flapping, bending, folding, sweeping, and twisting. However, the specific impact of these motions on the aerodynamic performance of wings throughout the wingbeat cycle, and their potential to inform engineering applications, remains insufficiently explored.
View Article and Find Full Text PDFSci Adv
December 2024
Wuhan National Laboratory for Optoelectronics and School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, Hubei, China.
Optical spin and orbital angular momenta are intrinsic characteristics of light determined by its polarization and spatial degrees of freedom, respectively. At the nanoscale, sharply focused structured light carries coupled spin-orbital angular momenta with complex 3D nearfield structures, crucial for manipulating multidimensional information of light in nanophotonics. However, characterizing these interactions faces challenges with conventional farfield-based methods, which typically lack the essential accuracy and resolution to interrogate the structured nearfield with high fidelity.
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