The electro-rotation (EROT) and electro-orientation (EOR) behavior of metallodielectric spherical Janus particles (JP) are studied analytically and verified experimentally. This stands in contrast to previous either heuristic or numerically computed models of JP dipoles. First, we obtain frequency-dependent analytic expressions for the corresponding dipole terms for a JP composed of dielectric and metallic hemispheres by applying the "standard" (weak-field) electrokinetic model and using a Fourier-Legendre collocation method for solving two sets of linear equations. EROT and EOR spectra, describing the variation of the JP's angular velocity on the forcing frequency of a rotating and nonrotating spatially uniform electric field, respectively, are explicitly determined and compared against experiments (different JP sizes and solution conductivities). While a favorably good agreement between theory and experimental measurements was found for the frequency response (∼8% difference), there is still a factor of ∼2 difference in the amplitude of the angular velocity, which necessitates further future improvements to the model.
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http://dx.doi.org/10.1021/acs.langmuir.2c02745 | DOI Listing |
Mol Pharm
January 2025
Key Laboratory of Natural Medicines of the Changbai Mountain, Ministry of Education, College of Pharmacy, Yanbian University, Yanji 133002, China.
The morbidity and mortality rates of hepatocellular carcinoma (HCC) are high and continue to increase. The antitumor effects of single therapies are limited because of tumor heterogeneity and drug resistance, and the lack of real-time monitoring of tumor progression during the treatment process leads to poor therapeutic outcomes. Therefore, novel nanodelivery platforms combining tumor therapy and diagnosis have garnered extensive attention.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Chemistry, Amrita School of Physical Sciences, Coimbatore, Amrita Vishwa Vidyapeetham, 641112, India; Functional Materials Laboratory, Amrita School of Engineering, Coimbatore, Amrita Vishwa Vidyapeetham, 641112, India. Electronic address:
The effectiveness and safety of nanomaterials (NMs) are essential for their use in healthcare. This study focuses on creating NPs with multifunctional antibacterial and anticancer properties to combat bacterial infections and cancer disease more effectively than traditional antibiotics. This study investigates the synthesis of ZrO and chitosan (ch) coated zirconium oxide nanoparticles (chZrO NPs) using Bougainvillea glabra (B.
View Article and Find Full Text PDFCell Rep Med
January 2025
Ben May Department for Cancer Research, The University of Chicago, Chicago, IL 60637, USA. Electronic address:
Metabolic reprogramming of tumor cells is an emerging hallmark of cancer. Among all the changes in cancer metabolism, increased glucose uptake and the accumulation of lactate under normoxic conditions (the "Warburg effect") is a common feature of cancer cells. In this study, we develop a lactate-responsive drug delivery platform by targeting the Warburg effect.
View Article and Find Full Text PDFRSC Adv
January 2025
Institute of Resources and Environmental Engineering, Shanxi University, Shanxi Yellow River Laboratory Taiyuan China
Coal combustion generates soot-type air pollution, and NO, as a typical pollutant, is the main haze-causing pollutant. The degradation of NO by means of photocatalytic superhydrophobic multifunctional coatings is both durable and economical. The precipitation method was employed to create a p-n type BiOBr/α-FeO photocatalytic binary system.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
College of Materials and Textile Engineering, Jiaxing University, Jiaxing 314001, China.
Programmable organization of uniform organic/inorganic functional building blocks into large-scale ordered superlattices has attracted considerable attention since the bottom-up self-organization strategy opens up a robust and universal route for designing novel and multifunctional materials with advanced applications in memory storage devices, catalysis, photonic crystals, and biotherapy. Despite making great efforts in the construction of superlattice materials, there still remains a challenge in the preparation of organic/inorganic hybrid superlattices with tunable dimensions and exotic configurations. Here, we report the spontaneous self-organization of polystyrene-tethered gold nanoparticles (AuNPs@PS) into freestanding organic/inorganic hybrid superlattices templated at the diethylene glycol-air interface.
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